Multifunctional Compound Combining Conductivity and Single-Molecule Magnetism in the Same Temperature Range

Inorganic Chemistry
Nataliya D KushchEduard B Yagubskii

Abstract

We report the first highly conducting single-molecule magnet, (BEDO)4[ReF6]·6H2O [1; BEDO = bis(ethylenedioxo)tetrathiafulvalene], whose conductivity and single-molecule magnetism coexist in the same temperature range. The compound was synthesized by BEDO electrocrystallization in the presence of (Ph4P)2[ReF6]·2H2O and characterized by crystallography and measurements of the conductivity and alternating-current magnetic susceptibility.

References

Jun 13, 2002·Journal of the American Chemical Society·Hideki FujiwaraAkiko Kobayashi
Nov 13, 2004·Chemical Reviews·Eugenio Coronado, Peter Day
May 17, 2008·Journal of the American Chemical Society·Nataliya D KushchWerner Biberacher
Jan 25, 2014·Angewandte Chemie·Kasper S PedersenJesper Bendix
Apr 13, 2017·Chemistry : a European Journal·Xuan ZhangKim R Dunbar
Aug 25, 2017·Nature·Conrad A P GoodwinDavid P Mills

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Citations

May 12, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Goulven CosquerMasahiro Yamashita

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