Multiphoton-excited luminescent lanthanide bioprobes: two- and three-photon cross sections of dipicolinate derivatives and binuclear helicates

The Journal of Physical Chemistry. B
Svetlana V EliseevaJean-Claude G Bünzli

Abstract

Multiphoton excited luminescent properties of water-soluble Eu(III) and Tb(III) complexes with derivatives of dipicolinic acid functionalized with a polyoxyethylene pendant arm and terminal groups, [Eu(L(OMe))(3)](3-), [Eu(L(NH2))(3)](3-), and [Tb(L(OH))(3)](3-), as well as of binuclear helicates with overall composition [Ln(2)(L(CX))(3)] (X = 2, 5) are investigated. Characteristic emission from the (5)D(0) and (5)D(4) excited levels of Eu(III) and Tb(III), respectively, upon approximately 800 nm excitation results from three-photon absorption (3PA) for [Eu(L(OMe))(3)](3-), [Eu(L(NH2))(3)](3-), [Tb(L(OH))(3)](3-), and [Ln(2)(L(C2))(3)], while luminescence from [Eu(2)(L(C5))(3)] is induced by two-photon absorption (2PA) owing to its 1PA spectrum extending further into the visible. The 3PA cross sections have been determined and are the first ones reported for lanthanide complexes: (i) those of Eu(III) and Tb(III) bimetallic helicates [Ln(2)(L(C2))(3)] are 20 times larger compared to the corresponding values for tris(dipicolinates); (ii) derivatization of dipicolinic acid for Tb(III) complexes has almost no influence on the 3PA cross section; however, for Eu(III) complexes a approximately 2 times decrease is observed. The feasibi...Continue Reading

References

Oct 1, 1996·Proceedings of the National Academy of Sciences of the United States of America·C XuW W Webb
May 15, 2007·Journal of the American Chemical Society·Langdon J MartinBarbara Imperiali
Sep 12, 2007·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Anthony D'AléoOlivier Maury
Dec 7, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Lars-Olof PålssonAndrew Beeby
Dec 22, 2007·Chemistry : a European Journal·Anne-Sophie ChauvinJean-Claude G Bünzli
Mar 7, 2008·Journal of the American Chemical Society·Ga-Lai LawPaul Kwan-Sing Lam
Jun 11, 2008·Optics Express·Nikolay S MakarovAleksander Rebane
Jul 4, 2008·Annals of the New York Academy of Sciences·Jean-Claude G BünzliSteve Comby
Jul 4, 2008·Annals of the New York Academy of Sciences·Pekka HänninenJuhani T Soini
Oct 31, 2008·Organic & Biomolecular Chemistry·Bo SongJean-Claude G Bünzli
Dec 10, 2008·Chemistry : a European Journal·Emmanuel DeitersJean-Claude G Bünzli
Feb 5, 2009·Accounts of Chemical Research·Craig P MontgomeryDavid Parker
Feb 19, 2009·Physical Chemistry Chemical Physics : PCCP·Annina AebischerJean-Claude G Bünzli
Mar 28, 2009·Accounts of Chemical Research·Evan G MooreKenneth N Raymond
Dec 22, 2009·Chemical Society Reviews·Svetlana V Eliseeva, Jean-Claude G Bünzli
Apr 17, 2001·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·J R LakowiczI Gryczynski

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Citations

May 20, 2011·Inorganic Chemistry·Yuen On FungWing-Tak Wong
Oct 23, 2013·Inorganic Chemistry·Megha RajendranLawrence W Miller
Aug 27, 2011·The Journal of Physical Chemistry. B·Mikhail Y BerezinSamuel Achilefu
Feb 11, 2014·Interface Focus·Jean-Claude G Bünzli
Feb 6, 2013·Biochemistry. Biokhimii︠a︡·V V Zherdeva, A P Savitsky
Jul 2, 2016·Inorganic Chemistry·Anh Thy BuiRaphaël Tripier
Nov 15, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·T M GeorgeM L P Reddy
May 11, 2017·Chemistry : a European Journal·Torsten SchwichMark G Humphrey
Feb 5, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Amit Kumar MondalSanjit Konar
Apr 14, 2016·Chemical Communications : Chem Comm·Octavia A BlackburnStephen Faulkner
Oct 19, 2017·Chemical Communications : Chem Comm·J H S K MonteiroA de Bettencourt-Dias
Nov 26, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Virginie PlacideOlivier Maury
Jan 16, 2015·Chemical Society Reviews·Angelo J Amoroso, Simon J A Pope
Apr 5, 2011·Angewandte Chemie·Lilit Aboshyan-SorghoClaude Piguet
Jun 29, 2010·Chemistry : a European Journal·Guangsheng ShaoYuan Wang
Sep 12, 2018·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Florian LiedyChristoph Riehn
May 30, 2020·Physical Chemistry Chemical Physics : PCCP·Patrick R NawrockiThomas Just Sørensen
Jul 23, 2013·Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry·Adrien BourdolleOlivier Maury
Jun 20, 2020·Physical Chemistry Chemical Physics : PCCP·Zhengming ZhangMing Li
Aug 12, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Adam W WoodwardKevin D Belfield
Mar 30, 2021·Chemistry : a European Journal·Laura Abad-GalánHubert Wadepohl
May 22, 2021·Journal of Medicinal Chemistry·Carime V RodriguesAna de Bettencourt-Dias
Jul 8, 2014·Inorganic Chemistry·Paula CucosMarius Andruh
Nov 5, 2011·Analytical Chemistry·Susmita DasIsiah M Warner

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