Multiple H2 occupancy of cages of clathrate hydrate under mild conditions

Journal of the American Chemical Society
Hailong LuJohn Ripmeester

Abstract

Experiments were carried out by reacting H(2) gas with N(2) hydrate at a temperature of 243 K and a pressure of 15 MPa. The characterizations of the reaction products indicated that multiple H(2) molecules can be loaded into both large and small cages of structure II clathrate hydrates. The realization of multiple H(2) occupancy of hydrate cages under moderate conditions not only brings new insights into hydrogen clathrates but also refreshes the perspective of clathrate hydrates as hydrogen storage media.

References

Sep 28, 2002·Science·Wendy L MaoYusheng Zhao
Oct 16, 2004·Science·Louw J FlorusseE Dendy Sloan
Apr 9, 2005·Nature·Huen LeeJohn A Ripmeester
Sep 14, 2007·Chemical Reviews·Viktor V StruzhkinRussell J Hemley
Sep 29, 2009·Journal of the American Chemical Society·Takeshi SugaharaCarolyn A Koh
Oct 8, 2009·Journal of the American Chemical Society·Jianwei WangJohn A Ripmeester

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Citations

May 31, 2013·Environmental Science & Technology·Sungwon ParkYongwon Seo
Jul 3, 2013·Physical Chemistry Chemical Physics : PCCP·Yang Song
Feb 28, 2020·Physical Chemistry Chemical Physics : PCCP·Hong ZhongJinxiang Liu
May 28, 2020·Physical Chemistry Chemical Physics : PCCP·Jinfeng Liu, Xiao He
Jun 21, 2013·Chemical Communications : Chem Comm·Dong-Yeun KohHuen Lee
Jan 3, 2013·Angewandte Chemie·Rajnish KumarJohn A Ripmeester
Jun 5, 2013·The Journal of Physical Chemistry. B·Andrey V IldyakovVladimir A Shestakov
Oct 15, 2019·The Journal of Physical Chemistry. B·Lizhi YiYouyuan Shao

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