N-Boc-L-valine-connected amidomonophosphane rhodium(I) catalyst for asymmetric arylation of N-tosylarylimines with arylboroxines

Journal of the American Chemical Society
Masami KuriyamaKiyoshi Tomioka

Abstract

A catalytic asymmetric arylation of sterically tuned imines with arylboroxines was developed by using N-Boc-l-valine-connected amidomonophosphane rhodium(I) catalyst in n-PrOH. The TMS group used for the steric tuning of imines is convertible to other functionalities that are applicable as a key foothold for the carbon-carbon bond-forming coupling reactions.

Citations

Jun 2, 2005·Chemical Communications : Chem Comm·Tomoya MiuraMasahiro Murakami
Jul 26, 2005·Chemical Communications : Chem Comm·Claude Y LegaultAndré B Charette
Aug 19, 2007·Chemical Communications : Chem Comm·Stefan BräseHenning Vogt
Jul 5, 2007·Chemical Communications : Chem Comm·Hiroshi Shimizu, Masahiro Murakami
Dec 18, 2007·Chemical Communications : Chem Comm·Tomoya MiuraMasahiro Murakami
Oct 29, 2008·Chemical Communications : Chem Comm·Khalid B SelimKiyoshi Tomioka
Aug 5, 2009·Chemical Communications : Chem Comm·Kazuhiro OkamotoViresh H Rawal
Apr 15, 2010·Chemical Communications : Chem Comm·Yong Luo, Jie Wu
Nov 7, 2015·Organic Letters·Jongrock KongRyan Mondschein
May 24, 2016·Organic Letters·Tomohiro YasukawaShu̅ Kobayashi
Jun 29, 2016·Organic Letters·Luis M Mori-Quiroz, Michael D Clift
Aug 10, 2016·Organic Letters·Tamara BeiselGeorg Manolikakes
Jun 14, 2017·Nature Communications·Philipp SchäferStephen P Fletcher
Feb 15, 2007·Chemical Communications : Chem Comm·Tomoya Miura, Masahiro Murakami
Dec 17, 2016·Chemical Communications : Chem Comm·Mao QuanWanbin Zhang
Jun 19, 2008·Angewandte Chemie·Gonzalo BlayJosé R Pedro
May 1, 2009·Advanced Synthesis & Catalysis·Barry M Trost, Andrew H Weiss
Mar 30, 2012·Chemical Society Reviews·Petr Stěpnička
Feb 24, 2011·Angewandte Chemie·Yang LiZhang-Jie Shi
Sep 22, 2019·Nature Protocols·Jesús GonzálezStephen P Fletcher
Jul 23, 2015·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Ken-Ichi Yamada, Kiyoshi Tomioka
Nov 10, 2017·Chemistry : a European Journal·Liang WuWanbin Zhang
Mar 13, 2016·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Sentaro Okamoto
Jan 29, 2010·Journal of the American Chemical Society·Guohua HouFrancis Gosselin

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.