N-Heterocyclic silylene/germylene ligands in Au(i) catalysis

Chemical Communications : Chem Comm
Nasrina ParvinShabana Khan

Abstract

Cationic Au(i) complexes (2, 5 and 8) supported by N-heterocyclic carbene, silylene and germylene ligands were prepared and their potential as catalysts in glycosidation chemistry has been evaluated. Insights into the mechanism are provided using DFT studies. Practical application of them as catalysts was achieved by the synthesis of the branched pentamannan core of the HIV-gp120 envelope under mild conditions.

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Citations

Jan 22, 2021·Chemistry : a European Journal·Ana ArauzoCarlos J Laglera-Gándara
Apr 23, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Jan ZechovskýLibor Dostál
Jun 18, 2021·Chemistry, an Asian Journal·Purva ChibdeMoumita Majumdar
Jul 9, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Moushakhi Ghosh, Shabana Khan

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Methods Mentioned

BETA
X-ray
glycosidation
glycosylation

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