Nanostructure and hydrogen spillover of bridged metal-organic frameworks

Journal of the American Chemical Society
Cheng-Si TsaoHsiu-Chu Wu

Abstract

The metal-organic frameworks (MOF) with low and medium specific surface areas (SSA) were shown to be able to adsorb hydrogen via bridged spillover at room temperature (RT) up to an amount of full coverage of hydrogen in the MOF. Anomalous small-angle X-ray scattering was employed to investigate the key relationship between the structures and storage properties of the involved materials. It was found that the tunable imperfect lattice defects and the 3D pore network in the MOF crystal are the most critical structures for RT hydrogen uptake rather than the known micropores in the crystal, SSA, and Pt catalyst structure.

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Citations

Apr 30, 2011·Chemical Communications : Chem Comm·George M Psofogiannakis, George E Froudakis
Sep 24, 2015·Physical Chemistry Chemical Physics : PCCP·Cheng-Yu WangAngela D Lueking
Apr 15, 2015·Nanoscale·Shaozhou Li, Fengwei Huo
Jul 23, 2015·Physical Chemistry Chemical Physics : PCCP·D PanayotovK Hadjiivanov
Mar 11, 2010·Advanced Materials·Chang LiuHui-Ming Cheng
Jun 4, 2015·Angewandte Chemie·Zhenlan FangRoland A Fischer
Aug 10, 2011·Chemistry : a European Journal·Thomas HügleDieter Lentz
Jan 23, 2013·Physical Chemistry Chemical Physics : PCCP·Jing-hua GuoXinlu Cheng
Jan 19, 2021·Physical Chemistry Chemical Physics : PCCP·Jing-Hua GuoGang Chen
Sep 28, 2010·Physical Review Letters·Kyuho LeeS B Zhang
Mar 5, 2010·Journal of the American Chemical Society·Yong YanMartin Schröder
Apr 21, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Adam F SapnikThomas D Bennett
Jun 10, 2010·Langmuir : the ACS Journal of Surfaces and Colloids·Nicholas R StuckertRalph T Yang
Mar 17, 2010·Langmuir : the ACS Journal of Surfaces and Colloids·Hao Chen, Ralph T Yang
Jun 19, 2013·Langmuir : the ACS Journal of Surfaces and Colloids·Jeremy I FeldblyumAdam J Matzger

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