Naphthocage: A Flexible yet Extremely Strong Binder for Singly Charged Organic Cations

Journal of the American Chemical Society
Fei JiaWei Jiang

Abstract

We report a quite flexible naphthol-based cage (so-called "naphthocage") which adopts a self-inclusion conformation in its free state and is able to bind singly charged organic cations extremely strongly ( Ka > 107 M-1). Ion-selective electrodes prepared with this naphthocage show a super-Nernstian response to acetylcholine. In addition, the highly stable complex (1010 M-1) between ferrocenium and the naphthocage can be switched electrochemically, which lays a basis for its application in stimuli-responsive materials.

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Citations

Jun 19, 2019·Chemical Communications : Chem Comm·Hongxin ChaiWei Jiang
Jul 30, 2019·Beilstein Journal of Organic Chemistry·Li-Li WangWei Jiang
Dec 21, 2019·Chemical Communications : Chem Comm·Song-Bo LuWei Jiang
Nov 7, 2019·Angewandte Chemie·Honghong DuanLiping Cao
Apr 8, 2020·Angewandte Chemie·Liu-Pan Yang, Wei Jiang
May 28, 2020·Chemical Society Reviews·Xiaoping WangWei Jiang
May 28, 2020·Chemical Communications : Chem Comm·Stephan SinnFrank Biedermann
Oct 28, 2020·Analytical Chemistry·Elena Zdrachek, Eric Bakker
Jul 21, 2020·Organic Letters·Rocco Del RegnoCarmine Gaeta
Mar 10, 2020·Journal of the American Chemical Society·Yukari TamuraMakoto Fujita
May 27, 2021·Angewandte Chemie·Xiang ZhaoChunju Li
Apr 4, 2020·Journal of the American Chemical Society·Wenqi LiuJ Fraser Stoddart
Jul 18, 2019·Journal of the American Chemical Society·Jia-Rui Wu, Ying-Wei Yang
Feb 6, 2020·Journal of the American Chemical Society·Fei JiaChristoph A Schalley

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