Navigating Organo-Lead Halide Perovskite Phase Space via Nucleation Kinetics toward a Deeper Understanding of Perovskite Phase Transformations and Structure-Property Relationships

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Spencer T WilliamsAlex K-Y Jen

Abstract

Organo-lead halide perovskite photovoltaics have developed faster than our understanding of the material itself. Using the vast body of work on perovskite processing created in just the past few years, it is possible to create a better picture of this material's complex phase-transformation behavior. This concept paper summarizes and correlates the current understanding of structural intermediates, kinetic controls, and structure-property relationships of organo-lead iodide perovskites. To this end, a new way of graphically relating information is developed, allowing the simultaneous mapping of schematic kinetic relationships between all currently prevailing perovskite deposition and growth techniques.

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Citations

Feb 13, 2016·The Journal of Physical Chemistry Letters·Spencer T WilliamsAlex K-Y Jen
Jan 2, 2016·The Journal of Physical Chemistry Letters·Yuxi TianIvan G Scheblykin
Jun 22, 2016·Chemical Reviews·Joseph S ManserPrashant V Kamat
Aug 10, 2016·Inorganic Chemistry·Jinli Yang, Timothy L Kelly
Jan 29, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Xin GuoClemens Burda
Feb 19, 2019·Physical Chemistry Chemical Physics : PCCP·Alonso W P SanchesSidney A Lourenço
Aug 29, 2018·Nature Communications·Kevin H StoneChristopher J Tassone
Jan 29, 2016·Nanotechnology·Carlito S PonsecaIvan G Scheblykin
Mar 18, 2021·Reports on Progress in Physics·Ziming ChenHin-Lap Yip
Oct 3, 2017·Nano Letters·Sebastian Z OenerErik C Garnett

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