NBN-embedded Polycyclic Aromatic Hydrocarbons Containing Pentagonal and Heptagonal Rings

Organic Letters
Yubin FuXinliang Feng

Abstract

Two novel nonhexagonal ring fused NBN-dibenzophenalenes (NBN-penta and NBN-hepta) were designed and synthesized. X-ray analysis reveals the planar structure of NBN-penta, while NBN-hepta displays a double-helical structure. Both compounds possess higher oxidation potential compared to the NBN-type zigzag-edged polycyclic aromatic hydrocarbons. The resultant NBN-penta and NBN-hepta exhibit global aromatic character based on X-ray analysis and DFT calculations. Furthermore, single crystal transistors of NBN-penta and NBN-hepta were fabricated, manifesting their promising potential in organic electronics.

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Citations

Mar 7, 2020·Angewandte Chemie·Yubin FuXinliang Feng
Jun 27, 2020·Chemistry : a European Journal·Xiaofeng WangFan Zhang

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