Nd3+ ,Ho3+ -Codoped apatite-related NaLa9 (GeO4 )6 O2 phosphors for the near- and middle-infrared region

Dalton Transactions : an International Journal of Inorganic Chemistry
Yana V BaklanovaVladimir G Zubkov

Abstract

The apatite-like NaLa9(GeO4)6O2:Nd3+,Ho3+ phosphor is prepared using the solid-state method. Rietveld refinement of high-resolution time-of-flight neutron powder diffraction measurements indicate that this compound crystallizes in the hexagonal system with space group P63/m, Z = 1 and unit cell parameters a = 9.88903(6) Å, c = 7.25602(5) Å, V = 614.521(7) Å3 at room temperature. The 4f sites are statistically occupied by La, Nd and Na, while 6h sites are occupied by La and Nd. Luminescence in the near- and middle-IR range caused by the transitions in neodymium and holmium ions is excited under 808 nm laser diode radiation. The highest emission intensity in NaLa9-x-yNdxHoy(GeO4)6O2 is attained at trace amounts of holmium, and it decreases sharply when y increases to 0.01. The IR phosphors have a good thermal stability and exhibit a very weak upconversion emission in the red spectral range upon 808 nm excitation. A scheme of excitation and emission pathways involving ground/excited state absorption, energy transfer, cross-relaxation, nonradiative multiphonon relaxation processes in Nd3+ and Ho3+ ions has been proposed. The data analysis indicates that Nd3+ ions serve as sensitizers for Ho3+ ions in these compounds, stimulating in...Continue Reading

References

Apr 15, 1996·Physical Review. B, Condensed Matter·P OrdejónJ M Soler
May 25, 2001·Acta Crystallographica. Section B, Structural Science·S Adams
Dec 12, 1964·Nature·M I KAYA S POSNER
Oct 4, 2004·Optics Express·Frédéric DruonPatrick Georges
May 25, 2012·The Journal of Physical Chemistry. a·Yanyan GuoJunjie Zhang
Mar 11, 2017·Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy·Yana V BaklanovaVladimir G Zubkov

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