New class of organic-inorganic hybrid aggregates based on polyoxometalates and metal-Schiff-base

Dalton Transactions : an International Journal of Inorganic Chemistry
Qiong WuEnbo Wang

Abstract

By combination of heteropolymolybdates and metal-Schiff-base complexes, two new organic-inorganic hybrid compounds {Mn(salen)(2)(H(2)O)(2)[AlMo(6)(OH)(6)O(18)]}[arg]·16H(2)O (1) and {Mn(salen)(2)(H(2)O)(2)[CrMo(6)(OH)(6)O(18)]}[arg]·11H(2)O (2) (salen = N,N'-ethylene-bis(salicylideneiminate) have been successfully isolated. Compounds 1 and 2 were structurally characterized by elemental analyses, IR spectra, thermogravimetric analysis, and single-crystal X-ray diffraction. To the best of our knowledge, compounds 1 and 2 represent the first single-crystal structures of metal-Schiff-base decorated polyoxometalates (POMs) compounds. Photocatalytic experiments indicated that both 1 and 2 exhibit high catalytic activity for photodegradation of RhB with UV irradiation. In addition, the magnetic properties of 1 were also investigated.

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Citations

Apr 24, 2012·Chemistry : a European Journal·Jingyang NiuJingping Wang
Sep 24, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiaopeng SunJingyang Niu
Jul 2, 2015·Inorganic Chemistry·He ZhangBai-Bin Zhou
Jun 24, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·He ZhangBai-bin Zhou
Jun 24, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhichao ShaoYaoting Fan
Dec 7, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Ying HuLin Wang
Apr 28, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Gonghao HuYan Xu
Aug 13, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Xiuli WangHongyan Lin
Aug 27, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Hai-Yan LiuHua Wu
Aug 7, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Wei-Qiu KanJian-Fang Ma

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