New concepts in multidentate ligand chemistry: effects of multidentarity on catalytic and spectroscopic properties of ferrocenyl polyphosphines

Chemical Society Reviews
Jean-Cyrille HiersoPhilippe Meunier

Abstract

This tutorial review devoted to ligand chemistry deals with the design and properties of ferrocenyl polyphosphines, an original class of multidentate ligands. The development of a varied library of ferrocenyl tetra-, tri- and diphosphine ligands is reviewed. The multidentate nature of these species has led to unique spectroscopic and catalytic properties, in which the spatial proximity of phosphorus atoms is crucial. Regarding their catalytic applications, the key issues of catalyst longevity and ultralow catalyst loadings are discussed. Another part is concerned with fundamental advances gained in physical chemistry for structure elucidation by the study of the intriguing "through-space" NMR spin-spin J couplings existing within several of these polyphosphines.

References

Mar 23, 2001·The Journal of Organic Chemistry·D LaurentiM Santelli
Jan 4, 2003·Chemical Communications : Chem Comm·Robin B BedfordMichael E Limmert

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Citations

May 6, 2011·Chemical Communications : Chem Comm·Laure MonnereauDominique Matt
Jul 12, 2011·Chemical Communications : Chem Comm·Elena ZaborovaMatthieu Sollogoub
May 20, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Lindsay J HounjetMartin Cowie
Mar 12, 2019·Chemical Communications : Chem Comm·Yeonkyeong RyuChristopher W Bielawski
Sep 12, 2015·Angewandte Chemie·Chuanhu LeiJianrong Steve Zhou
Aug 7, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Ali JahelJean-Cyrille Hierso
Jul 26, 2019·The Journal of Organic Chemistry·Jia-Chen XiangShu-Li You

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