New cuprates featuring ladderlike periodic arrays of [Cu3O8]10- trimeric magnetic nanostructures

Inorganic Chemistry
Xunhua MoQun Huang

Abstract

A new family of cuprates, Li2Cu3(SiO3)4 (1) and Na2Cu3(GeO3)4 (2), was isolated in molten salt media. The extended lattices contain ladderlike periodic arrays of [Cu3O8]10- magnetic nanostructures. Magnetic properties of the Na2Cu3Ge(4-x)SixO12 series, where x = 0, 0.86, and 1.72, were systematically studied. The geometrically induced magnetic couplings are tunable upon cation substitution.

References

Apr 25, 2002·Journal of the American Chemical Society·Younghwa NaHarold Kohn

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Citations

Jul 16, 2010·Acta Crystallographica. Section B, Structural Science·Paul F HenryDimitri N Argyriou
May 29, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Xue-Li CaoJiang-Gao Mao
Oct 31, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Yue-Ling BaiJun Tao
Apr 13, 2007·Inorganic Chemistry·Shilie PanKenneth R Poeppelmeier

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