New Phenomena in Organometallic-Mediated Radical Polymerization (OMRP) and Perspectives for Control of Less Active Monomers

Chemistry : a European Journal
Rinaldo Poli

Abstract

The impact of reversible bond formation between a growing radical chain and a metal complex (organometallic-mediated radical polymerization (OMRP) equilibrium) to generate an organometallic intermediate/dormant species is analyzed with emphasis on the interplay between this and other one-electron processes involving the metal complex, which include halogen transfer in atom transfer radical polymerization (ATRP), hydrogen-atom transfer in catalytic chain transfer (CCT), and catalytic radical termination (CRT). The challenges facing the controlled polymerization of "less active monomers" (LAMs) are outlined and, after reviewing the recent achievements of OMRP in this area, the perspectives of this technique are analyzed.

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Apr 28, 2017·Inorganic Chemistry·Timothy J Zerk, Paul V Bernhardt
May 10, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Benjamin R M Lake, Michael P Shaver
Aug 15, 2015·Chemical Communications : Chem Comm·Jérémy DemarteauChristophe Detrembleur
Sep 20, 2018·Chemistry : a European Journal·Roberto Morales-CerradaRinaldo Poli
Apr 9, 2020·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Sajjad Dadashi-Silab, Krzysztof Matyjaszewski
Jan 13, 2021·Macromolecular Rapid Communications·Hugo Fouilloux, Christophe M Thomas
Feb 2, 2021·Chemical Science·Sophia L ShevickRyan A Shenvi
Jun 17, 2021·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Wachara Benchaphanthawee, Chi-How Peng
Nov 6, 2021·Journal of the American Chemical Society·Yajun ZhaoKyoko Nozaki

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