NH2-MIL-53(Al): a high-contrast reversible solid-state nonlinear optical switch

Journal of the American Chemical Society
Pablo Serra-CrespoJorge Gascon

Abstract

The metal-organic framework NH(2)-MIL-53(Al) is the first solid-state material displaying nonlinear optical switching due to a conformational change upon breathing. A switching contrast of at least 38 was observed. This transition originates in the restrained linker mobility in the very narrow pore configuration.

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Jul 20, 2013·Accounts of Chemical Research·Frédéric CastetBenoît Champagne
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Aug 16, 2012·Langmuir : the ACS Journal of Surfaces and Colloids·Pablo Serra-CrespoJorge Gascon

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