Ni-Catalyzed direct 1,4-difunctionalization of [60]fullerene with benzyl bromides

Chemical Communications : Chem Comm
Weili SiTienan Jin

Abstract

A new Ni-catalyzed direct 1,4-difunctionalization of [60]fullerene with various benzyl bromides has been developed. The use of a DMSO additive combined with a nickel catalyst is indispensable for the formation of 1,4-dibenzyl fullerenes with a variety of functional groups. The reaction proceeds through the formation of a fullerene monoradical species.

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Nov 5, 2014·Chemical Communications : Chem Comm·Weili SiTienan Jin

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Citations

Jan 16, 2016·The Journal of Organic Chemistry·Hai-Tao YangChun-Bao Miao
May 12, 2017·The Journal of Organic Chemistry·Hai-Tao YangChun-Bao Miao
Sep 28, 2017·Organic & Biomolecular Chemistry·Michio YamadaYutaka Maeda
Sep 14, 2017·The Journal of Organic Chemistry·Sheng-Peng JiangGuan-Wu Wang

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