Nickel-catalyzed amination of aryl tosylates

The Journal of Organic Chemistry
Cai-Yan Gao, Lian-Ming Yang

Abstract

The cross-coupling of aryl tosylates with amines and anilines was accomplished by using a Ni-based catalyst system from the combination of Ni(II)-(sigma-aryl) complexes/N-heterocyclic carbenes (NHCs). The feature, scope, and limitation of this reaction are disclosed.

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