NIST Standards for Measurement, Instrument Calibration, and Quantification of Gaseous Atmospheric Compounds

Analytical Chemistry
George C RhoderickJoseph T Hodges

Abstract

There are many gas phase compounds present in the atmosphere that affect and influence the earth's climate. These compounds absorb and emit radiation, a process which is the fundamental cause of the greenhouse effect. The major greenhouse gases in the earth's atmosphere are carbon dioxide, methane, nitrous oxide, and ozone. Some halocarbons are also strong greenhouse gases and are linked to stratospheric ozone depletion. Hydrocarbons and monoterpenes are precursors and contributors to atmospheric photochemical processes, which lead to the formation of particulates and secondary photo-oxidants such as ozone, leading to photochemical smog. Reactive gases such as nitric oxide and sulfur dioxide are also compounds found in the atmosphere and generally lead to the formation of other oxides. These compounds can be oxidized in the air to acidic and corrosive gases and contribute to photochemical smog. Measurements of these compounds in the atmosphere have been ongoing for decades to track growth rates and assist in curbing emissions of these compounds into the atmosphere. To accurately establish mole fraction trends and assess the role of these gas phase compounds in atmospheric chemistry, it is essential to have good calibration stan...Continue Reading

References

Dec 11, 2003·Chemical Reviews·Roger Atkinson, Janet Arey
Aug 3, 2005·Analytical and Bioanalytical Chemistry·George C Rhoderick
Apr 4, 2006·Analytical Chemistry·Tyler B CoplenR Michael Verkouteren
Jan 8, 2010·Analytical Chemistry·George C RhoderickKathryn DeSirant
Mar 30, 2012·Analytical Chemistry·George C RhoderickFranklin R Guenther
Feb 22, 2014·Analytical Chemistry·George C RhoderickDaniel Riemer
Dec 19, 2014·Analytical Chemistry·Walter R MillerFranklin R Guenther
Dec 10, 2015·Analytical and Bioanalytical Chemistry·George C RhoderickAntonio Possolo
Jan 12, 2016·Elementa : Science of the Anthropocene·George C RhoderickRay F Weiss
Feb 19, 2016·Analytical Chemistry·George C RhoderickJennifer Carney

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