Nitroxide spin exchange due to re-encounter collisions in a series of n-alkanes.

The Journal of Chemical Physics
Mark R KurbanBarney L Bales

Abstract

Bimolecular collisions between perdeuterated 2,2,6,6-tetramethyl-4-oxopiperidine-l-oxyl molecules in three alkanes have been studied by measuring the electron paramagnetic resonance (EPR) spectral changes induced by spin exchange. We define an "encounter" to be a first-time collision followed by a series of re-encounters prior to the diffusing pair's escaping each other's presence. The present work stems from a recent proposal [B. L. Bales et al., J. Phys. Chem. A 107, 9086 (2003)] that an unexpected linear dependence of the spin-exchange-induced EPR line shifts on spin-exchange frequency can be explained by re-encounters of the same probe pair during one encounter. By employing nonlinear least-squares fitting, full use of the information available from the spectral changes allows us to study encounters and re-encounters separately. The encounter rate constants appear to be dominated by hydrodynamic forces, forming a common curve for hexane, decane, and hexadecane when plotted against T/eta, where eta is the shear viscosity. Unexpectedly, encounters are not dependent on the ratio mu = a/a(s), where a and a(s) are the van der Waals radii of the nitroxide probe and the solvent, respectively. It is argued that the near coincidence...Continue Reading

References

May 26, 1999·Journal of Magnetic Resonance·B H RobinsonA W Reese
May 26, 1999·Journal of Magnetic Resonance·B H RobinsonA W Reese
Feb 1, 1955·American Journal of Ophthalmology·J K FRENKEL
Jun 13, 2008·Journal of Magnetic Resonance·Wojciech FronciszJames S Hyde

❮ Previous
Next ❯

Citations

Feb 18, 2014·The Journal of Physical Chemistry. B·Bruce A KowertNhan C Dang
Jul 26, 2011·The Journal of Physical Chemistry. B·Bruce A Kowert, Michael B Watson
Aug 12, 2021·The Journal of Physical Chemistry. B·B Y Mladenova KattnigA I Kokorin
Jan 17, 2015·The Journal of Physical Chemistry. B·Dalibor MerunkaMiroslav Peric
Dec 20, 2011·The Journal of Physical Chemistry. a·Reinhard StösserAnita Pahlke
Aug 30, 2012·The Journal of Physical Chemistry. B·Boryana Y MladenovaDaniel R Kattnig

❮ Previous
Next ❯

Methods Mentioned

BETA
electron paramagnetic resonance

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.