N,N'-Methylenebis(N-(1,2,5-oxadiazol-3-yl)nitramide) derivatives as metal-free green primary explosives

Dalton Transactions : an International Journal of Inorganic Chemistry
Qiong YuJean'ne M Shreeve

Abstract

A series of new energetic salts based on N,N'-methylenebis(N-(4-(dinitromethyl)-1,2,5-oxadiazol-3-yl)nitramide) was synthesized and fully characterized by NMR and IR spectroscopy, and elemental analysis. Their excellent vD (7995-8885 m s-1) and acceptable sensitivities (IS, 1-5 J; FS, 40-120 N) make them good candidates as metal-free green primary explosives (with the exception of 3).

References

Apr 30, 2002·Inorganic Chemistry·H Donald Brooke JenkinsLeslie Glasser
Apr 17, 2014·Chemistry : a European Journal·Dennis FischerJörg Stierstorfer
May 9, 2014·Chemistry : a European Journal·Marcos A KettnerSwetlana Wunder
Jun 23, 2015·Angewandte Chemie·Dennis FischerJörg Stierstorfer
Aug 12, 2015·Journal of the American Chemical Society·Jiaheng ZhangJean'ne M Shreeve
Jun 20, 2017·Journal of the American Chemical Society·Qiong YuJean'ne M Shreeve
Oct 12, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Qiong YuHongwei Yang
Nov 11, 2017·Chemistry : a European Journal·Qiong YuJean'ne M Shreeve

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Methods Mentioned

BETA
differential scanning calorimetric
scraping
NMR
nuclear magnetic resonance

Software Mentioned

SHELXL
Explo5
XPREP
Gaussian
SADABS
WingX
SAINT
APEX2

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