Non-classical divalent lanthanide complexes

Dalton Transactions : an International Journal of Inorganic Chemistry
François Nief

Abstract

The synthesis of non-classical divalent lanthanide complexes, i.e. those not containing the classical samarium(II), europium(II) or ytterbium(II), was once thought impossible. Since 1997, when the first stable complex of thulium(II) was discovered, there has been many more examples of stable coordination and organometallic complexes of lanthanum(II), neodymium(II) and dysprosium(II) in addition to thulium(II), and the influence of the ligand system on the stability of the complexes is beginning to be understood. These non-classical divalent compounds show exceptional reactivity as some of them have been shown to activate dinitrogen at room temperature, together with related reduced divalent-like systems, and to undergo spontaneous intramolecular carbon-hydrogen bond activation. Many more examples of non-classical divalent compounds together with new aspects of their exciting reactivity should be discovered in the near future.

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Citations

Apr 30, 2013·Inorganic Chemistry·Brian D MahoneyEric J Schelter
Oct 12, 2011·Chemical Communications : Chem Comm·Aurélien MominFrançois Nief
Jun 21, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Ludovic CastroLaurent Maron
Apr 25, 2014·Chemical Reviews·Michal SzostakDavid J Procter
May 16, 2012·Journal of the American Chemical Society·Matthew R MacDonaldWilliam J Evans
May 24, 2013·Journal of the American Chemical Society·Matthew R MacDonaldWilliam J Evans
Nov 5, 2016·Journal of Critical Care·Peter G BrindleyDimitrios Karakitsos
Mar 2, 2017·Angewandte Chemie·Mathieu XémardGrégory Nocton
Apr 22, 2017·Chemistry : a European Journal·Andreas Uwe MeyerBurkhard König
Jun 29, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Mathieu XémardGrégory Nocton
Oct 11, 2012·European Journal of Inorganic Chemistry·Joel Garcia, Matthew J Allen
Aug 1, 2014·Angewandte Chemie·Julie AndrezMarinella Mazzanti
Nov 16, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Grégory Nocton, Louis Ricard
May 6, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Jingjing LiuDavid P Mills
Aug 16, 2012·Angewandte Chemie·Michal Szostak, David J Procter
Aug 30, 2019·Chemistry Squared·Arnaud JaoulGrégory Nocton
Jan 17, 2021·Chemistry : a European Journal·David P Mills, Peter Evans
Dec 20, 2020·Chemistry : a European Journal·Maxime TricoireGrégory Nocton
Jun 15, 2021·Chemical Science·Benjamin L L RéantDavid P Mills
Feb 7, 2019·Inorganic Chemistry·Mathieu XémardGrégory Nocton
Oct 9, 2018·Journal of the American Chemical Society·Mathieu XémardGrégory Nocton
Oct 26, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Song XuWilliam J Evans

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