Non-racemic (scalemic) planar-chiral five-membered metallacycles: routes, means, and pitfalls in their synthesis and characterization

Chemical Society Reviews
Jean-Pierre DjukicGérald Bernardinelli

Abstract

This critical review provides a systematic classification of the synthetic routes to planar-chiral five-membered metallacycles into several routes, namely C-H bond activation, oxidative addition, transmetallation and optical resolution. As a characteristic of these bulk compounds is that they are synthesized as binary mixtures of enantiomers in proportions varying from the racemate to enantiopure, a review of absolute-configuration determination of the title planar-chiral scalemates is presented. This review is of interest to organic and organometallic synthetic chemists involved in asymmetric synthesis (97 references).

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Citations

Oct 29, 2008·Chemical Communications : Chem Comm·Kévin M JolyChristopher J Moody
Feb 15, 2011·Chemical Communications : Chem Comm·Jean-Pierre DjukicXavier-Frédéric Le Goff
Jun 21, 2011·Chemical Communications : Chem Comm·Alfonso LatorreM Carmen Carreño
Jan 15, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Anant R Kapdi
Apr 1, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Jean-Pierre DjukicXavier-Frédéric Le Goff
Oct 12, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·David AguilarEsteban P Urriolabeitia
Mar 19, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Matthew J FuchterAndrew J P White
Jan 26, 2016·Chemistry : a European Journal·Ross A ArthursChristopher J Richards
Apr 10, 2012·European Journal of Medicinal Chemistry·Nikodem KuźnikMaciej Kubicki
Feb 21, 2009·Chemistry : a European Journal·Sylvestre BonnetRobertus J M Klein Gebbink
Apr 25, 2013·Chemistry : a European Journal·Manuel WeberRené Peters
Sep 29, 2012·Chemistry : a European Journal·Manuel WeberRené Peters
Jul 14, 2010·Chemistry, an Asian Journal·Hiroshi Nomura, Christopher J Richards
Nov 5, 2013·Journal of the American Chemical Society·Christophe WerléJean-Pierre Djukic
Oct 31, 2013·The Journal of Physical Chemistry. B·Piotr PaluchMarek J Potrzebowski
Aug 19, 2010·Journal of the American Chemical Society·Manuel WeberRené Peters
Nov 25, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Ismael MarcosJosé M Vila
Oct 3, 2018·Chemistry : a European Journal·Kazuhiro Yoshida, Risa Yasue
Oct 20, 2018·ChemistryOpen·Adolfo Fernández-FigueirasJosé M Vila

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