Nonionic urea surfactants: influence of hydrocarbon chain length and positional isomerism on the thermotropic and lyotropic phase behavior

The Journal of Physical Chemistry. B
Darrell WellsCalum J Drummond

Abstract

The thermotropic and lyotropic phase behavior of 1- and 5-decyl urea, and 1-, 2-, 4-, and 6-dodecyl urea have been studied. This allowed the effect of positional isomerism to be examined. Intermolecular hydrogen bonding by the urea moiety is the dominant factor in determining the solid-state thermal behavior and crystal solubility boundary of these linear nonionic surfactants. The positional isomers where the urea moiety was not situated at the terminus of the hydrocarbon chain exhibited higher melting points than the 1-alkyl ureas. This has been rationalized by postulating interdigitated chains in the solid state. In the urea surfactant-water systems, three phases are observed, viz. crystalline solid, a dilute aqueous solution of the alkyl urea, and an isotropic liquid. The last two phases coexist in the low-surfactant, high-temperature region of the binary phase diagram. An overview of structure-property correlations for linear nonionic urea surfactants is presented in light of the new physicochemical data obtained for the decyl urea and dodecyl urea positional isomers.

References

Oct 6, 2000·Journal of Colloid and Interface Science·R Stosch, H K Cammenga
Feb 17, 2005·Journal of Molecular Biology·Anna L Mallam, Sophie E Jackson
May 24, 2005·Biophysical Journal·Ana Caballero-HerreraLennart Nilsson
May 26, 2005·Journal of Colloid and Interface Science·Asima ChakrabortySoumen Basak
Jun 2, 2005·Archives of Biochemistry and Biophysics·Basir AhmadRizwan Hasan Khan
Jun 7, 2005·Protein Science : a Publication of the Protein Society·Limin Wang, Wilfredo Colón

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Citations

Nov 9, 2006·Physical Chemistry Chemical Physics : PCCP·Thomas Kaasgaard, Calum J Drummond
Aug 14, 2020·Chemistry : a European Journal·Filippo TosiBen L Feringa
Jan 23, 2009·The Journal of Physical Chemistry. B·Célia M C FaustinoLuís Garcia-Rio
Nov 26, 2009·Langmuir : the ACS Journal of Surfaces and Colloids·Sharon M SagnellaCalum J Drummond

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