Novel applications of alkenyl zirconocenes

Chemistry : a European Journal
Peter Wipf, Christopher Kendall

Abstract

Alkenyl zirconocene complexes are readily obtained by diverse processes including hydrozirconation, carbozirconation, and cyclozirconation of alkynes, transmetalations, and bond insertions. In combination with other metals, novel reaction manifolds can emerge and provide access to useful synthetic building blocks. Both catalytic asymmetric processes and highly diastereoselective multicomponent transformations that involve the formation of three or more new carbon-carbon bonds are feasible. This Concept paper summarizes the current state of the art and opportunities for future reaction discovery in this field of research, with particular emphasis on synergistic effects of bimetallic combinations of zirconocenes and zinc.

Citations

Sep 29, 2012·Beilstein Journal of Organic Chemistry·Bettina MillerPeter Wipf
May 4, 2016·Journal of the American Chemical Society·Yuan HuangYu Zhao
May 27, 2017·Organic Letters·Elena Yu SchmidtBoris A Trofimov
Aug 28, 2004·Organic Letters·Peter WipfMaciej A A Walczak
Apr 21, 2018·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Ricard SolàBeatriz Maciá
Sep 17, 2013·Chemistry : a European Journal·Chandi C MalakarKourosch Abbaspour Tehrani
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