Novel mu5-coordination modes of aryl and alkyl ethynides and classification of metal-ligand interactions in silver(I) complexes

Chemistry : a European Journal
Liang ZhaoThomas C W Mak

Abstract

Novel mu(5)-eta(1),eta(1),eta(1),eta(1),eta(2) and mu(5)-eta(1),eta(1),eta(1),eta(2),eta(2) coordination modes of alkyl and aryl ethynide moieties are found in silver(I) complexes 1-5, and the metal-ligand distances can be classified into sigma, pi and mixed (sigma,pi) types. With the consistent square-pyramidal capping Ag(5) baskets of the ethynide moiety as supramolecular synthons, a series of two- and three-dimensional coordination networks are obtained.

References

Oct 10, 2001·Angewandte Chemie·Daniela RaisDavid J. Williams
May 8, 1997·Chemical Reviews·Pekka Pyykkö
Sep 19, 2003·Chemical Communications : Chem Comm·Qiao-Hua WeiZhong-Ning Chen
Dec 18, 2003·Journal of the American Chemical Society·Wei LuChi-Ming Che
May 25, 2004·Inorganic Chemistry·Qiao-Hua WeiZhong-Ning Chen
Jun 4, 2004·Journal of the American Chemical Society·Liang Zhao, Thomas C W Mak
Jan 12, 2005·Chemical Society Reviews·Katharina ReichenbächerJurg Hulliger
Nov 3, 2000·Angewandte Chemie·Christopher P McArdleRichard J Puddephatt

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Citations

Nov 14, 2014·Angewandte Chemie·Hubert Schmidbaur, Annette Schier
Aug 29, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Jun-Ling JinXing Lu
Sep 18, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Tianle ZhangXianggao Meng
Jun 13, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Kun ZhouZhong-Min Su
Aug 27, 2014·Chemical Communications : Chem Comm·Kun ZhouYing-Ning Yu
Apr 19, 2007·Chemistry, an Asian Journal·Thomas C W Mak, Liang Zhao
May 13, 2011·Journal of the American Chemical Society·Cai-Yan GaoMei-Xiang Wang

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