Novel N6 trisbidentate ligand coordinated Ir(iii) complexes and their Ru(ii) analogs

Dalton Transactions : an International Journal of Inorganic Chemistry
Li WangWenfang Sun

Abstract

Novel N6-coordinated Ir(iii) complexes bearing polypyridyl ligands were synthesized and characterized. In comparison to their Ru(ii) analogs, these Ir(iii) complexes showed blue-shifted UV-vis absorption and emission spectra, but dramatically increased triplet lifetimes with much broader and stronger triplet excited-state absorption.

References

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