Novel trans-spanned palladium complexes as efficient catalysts in mild and amine-free cyanation of aryl bromides under air

Organic Letters
Olga Grossman, Dmitri Gelman

Abstract

[reaction: see text] The use of a novel trans-spanned palladium complex as an efficient and selective catalyst in the cyanation of aryl halides is described. The suggested reaction conditions are mild, exhibit good scope of substrates, and circumvent the need for an inert atmosphere and amine co-ligands.

References

May 1, 1986·Journal of Medicinal Chemistry·D W RobertsonJ S Hayes
Mar 6, 2003·Journal of the American Chemical Society·Jacopo ZanonStephen L Buchwald
Apr 17, 2003·Chemistry : a European Journal·Mark SundermeierMatthias Beller
Apr 17, 2003·Angewandte Chemie·Mark SundermeierMatthias Beller
Jun 5, 2004·Chemical Communications : Chem Comm·Thomas SchareinaMatthias Beller
Feb 12, 2005·The Journal of Organic Chemistry·Steven A WeissmanCheng Chen
Aug 1, 1988·Journal of the American Chemical Society·T M HarrisJ Y Lee

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Citations

Jun 27, 2015·The Journal of Organic Chemistry·Lodi Mahendar, Gedu Satyanarayana
Jul 14, 2016·The Journal of Organic Chemistry·Aniket MishraIndubhusan Deb
Aug 16, 2016·Organic Letters·Ryosuke TakiseJunichiro Yamaguchi
Dec 10, 2016·The Journal of Organic Chemistry·Arumugam VigneshNallasamy Dharmaraj
Jan 20, 2015·Organic & Biomolecular Chemistry·Chu-Ting YangXiaolin Wang
Oct 21, 2015·Angewandte Chemie·Christian A MalapitChris H Senanayake
Oct 6, 2018·Organic & Biomolecular Chemistry·Alexander M Nauth, Till Opatz
May 8, 2007·Chemistry : a European Journal·Thomas SchareinaMatthias Beller
Mar 24, 2010·Chemistry : a European Journal·Pazhamalai AnbarasanMatthias Beller
Dec 7, 2010·Angewandte Chemie·Pazhamalai AnbarasanMatthias Beller
Mar 10, 2011·Chemistry : a European Journal·Pazhamalai AnbarasanMatthias Beller
Feb 7, 2012·Chemical Communications : Chem Comm·Dengyou ZhangHong Liu
Nov 8, 2012·Angewandte Chemie·Jinho KimSukbok Chang
Aug 13, 2013·Angewandte Chemie·Todd D SenecalStephen L Buchwald
Jan 10, 2014·Chemical Communications : Chem Comm·Weiping Liu, Lutz Ackermann
Nov 19, 2014·Angewandte Chemie·Jie Li, Lutz Ackermann
Nov 2, 2017·Chemistry : a European Journal·Shaoke ZhangMatthias Beller
Jan 7, 2011·Organic Letters·Pui Yee YeungFuk Yee Kwong
Dec 31, 2010·The Journal of Organic Chemistry·Hannah YuScott A May
Jul 5, 2013·Journal of the American Chemical Society·Tian-Jun GongYao Fu
May 27, 2014·The Journal of Organic Chemistry·Tanmay ChatterjeeBrindaban C Ranu
Aug 15, 2006·Inorganic Chemistry·Clarite AzerrafDmitri Gelman
Sep 30, 2021·Organic & Biomolecular Chemistry·Lu WangJiang Cheng

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