Observation of Interpenetration Isomerism in Covalent Organic Frameworks

Journal of the American Chemical Society
Tianqiong MaWei Wang

Abstract

We report herein the first example of interpenetration isomerism in covalent organic frameworks (COFs). As a well-known three-dimensional (3D) COF, COF-300 was synthesized and characterized by the Yaghi group in 2009 as a 5-fold interpenetrated diamond structure ( dia-c5 topology). We found that adding an aging process prior to the reported synthetic procedure afforded the formation of an interpenetration isomer, dia-c7 COF-300. The 7-fold interpenetrated diamond structure of this new isomer was identified by powder X-ray diffraction and rotation electron diffraction analyses. Furthermore, we proposed a universal formula to accurately determine the number of interpenetration degrees of dia-based COFs from only the unit cell parameters and the length of the organic linker. This work not only provides a novel example to the category of interpenetration isomerism but also provides new insights for the further development of 3D COFs.

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Citations

Jul 31, 2019·Chemical Society Reviews·Liang FengHong-Cai Zhou
Jan 30, 2020·Chemical Society Reviews·Zhifang WangShengqian Ma
Jul 30, 2020·Chemical Society Reviews·Xing HanYong Cui
Mar 20, 2020·Nature Communications·Hai-Sen XuKian Ping Loh
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Dec 12, 2018·Nature Communications·Youshi LanChongli Zhong
Dec 15, 2018·Angewandte Chemie·Penghao LiJ Fraser Stoddart
Dec 2, 2020·Nature Communications·Tianqiong MaWei Wang
Nov 28, 2020·Angewandte Chemie·Yusen LiLong Chen
Nov 7, 2020·Chemical Society Reviews·Frederik Haase, Bettina V Lotsch
Feb 24, 2021·Nature Nanotechnology·Jianyuan LiFeng Pan
Feb 9, 2021·Angewandte Chemie·Marta Martínez-AbadíaAurelio Mateo-Alonso
Feb 14, 2020·Journal of the American Chemical Society·Yujie WangQianrong Fang
May 20, 2021·Chemical Communications : Chem Comm·Yang-Hui LuoLi-Hai Zhai
Sep 9, 2020·Accounts of Chemical Research·Bo GuiCheng Wang
Jul 1, 2020·Journal of the American Chemical Society·Peng CuiAndrew I Cooper
Jan 19, 2019·Journal of the American Chemical Society·Yichong ChenYue-Biao Zhang
Aug 26, 2020·Journal of the American Chemical Society·Xing KangYong Cui
May 16, 2019·Journal of the American Chemical Society·Jinjing HuangYong Cui
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Dec 17, 2019·The Journal of Physical Chemistry Letters·Youliang ZhuZhao-Yan Sun
Sep 18, 2021·Journal of the American Chemical Society·Shitao WangDapeng Cao
Aug 12, 2021·Angewandte Chemie·Rongran LiangChenfeng Ke

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