Octacyanidometallates for multifunctional molecule-based materials

Chemical Society Reviews
Szymon ChorazyBarbara Sieklucka

Abstract

Octacyanidometallates have been successfully employed in the design of heterometallic coordination systems offering a spectacular range of desired physical properties with great potential for technological applications. The [M(CN)8]n- ions comprise a series of complexes of heavy transition metals in high oxidation states, including NbIV, MoIV/V, WIV/V, and ReV. Since the discovery of the pioneering bimetallic {MnII4[MIV(CN)8]2} and {MnII9[MV(CN)8]6} (M = Mo, W) molecules in 2000, octacyanidometallates were fruitfully explored as precursors for the construction of diverse d-d or d-f coordination clusters and frameworks which could be obtained in the crystalline form under mild synthetic conditions. The primary interest in [M(CN)8]n--based networks was focused on their application as molecule-based magnets exhibiting long-range magnetic ordering resulting from the efficient intermetallic exchange coupling mediated by cyanido bridges. However, in the last few years, octacyanidometallate-based materials proved to offer varied and remarkable functionalities, becoming efficient building blocks for the construction of molecular nanomagnets, magnetic coolers, spin transition materials, photomagnets, solvato-magnetic materials, includin...Continue Reading

References

May 3, 1996·Science·O SatoK Hashimoto
Mar 7, 2002·Journal of the American Chemical Society·Laurance G Beauvais, Jeffrey R Long
Jul 19, 2002·Chemical Communications : Chem Comm·Robert PodgajnyBarbara Sieklucka
Jan 28, 2003·Angewandte Chemie·Dante Gatteschi, Roberta Sessoli
Feb 27, 2003·Journal of the American Chemical Society·Miriam V Bennett, Jeffrey R Long
Apr 17, 2003·Chemistry : a European Journal·Valérie MarvaudMichel Verdaguer
Jul 17, 2003·Journal of the American Chemical Society·Naoto IshikawaYoukoh Kaizu
Aug 2, 2003·Journal of the American Chemical Society·Yoichi ArimotoKazuhito Hashimoto
Dec 4, 2003·Chemical Communications : Chem Comm·Shin-ichi OhkoshiKazuhito Hashimoto
Apr 22, 2004·Journal of the American Chemical Society·Toshinori KashiwagiKazuhito Hashimoto
Nov 24, 2004·Nature Materials·Shin-Ichi OhkoshiKazuhito Hashimoto
Feb 3, 2005·Chemical Communications : Chem Comm·Laure CatalaTalal Mallah
Feb 11, 2005·Dalton Transactions : an International Journal of Inorganic Chemistry·Julie Clarissa F ColisHoward Patterson
Mar 18, 2005·Journal of the American Chemical Society·You SongXiao-Zeng You
Aug 18, 2005·Journal of the American Chemical Society·Tomohiro NuidaShin-Ichi Ohkoshi
Jan 5, 2006·Journal of the American Chemical Society·Shin-ichi OhkoshiFrançoise Villain
Mar 4, 2006·Science·A S MischenkoN D Mathur
May 23, 2006·Inorganic Chemistry·Jeffrey R WithersStephen M Holmes
Jun 6, 2006·Dalton Transactions : an International Journal of Inorganic Chemistry·Robert PodgajnyBarbara Sieklucka
Jun 6, 2006·Dalton Transactions : an International Journal of Inorganic Chemistry·Danna E FreedmanJeffrey R Long
Feb 21, 2007·Journal of the American Chemical Society·Constantinos J MiliosEuan K Brechin
Feb 22, 2007·Journal of the American Chemical Society·Shin-ichi OhkoshiKazuhito Hashimoto
Mar 8, 2007·Journal of the American Chemical Society·Nobuhiro YanaiSusumu Kitagawa
Mar 9, 2007·Journal of the American Chemical Society·Daniela BrinzeiTalal Mallah
Mar 10, 2007·Chemical Communications : Chem Comm·Anthony K CheethamRussell K Feller
Aug 24, 2007·Journal of the American Chemical Society·Juan-Manuel HerreraMichael D Ward

❮ Previous
Next ❯

Citations

Jan 26, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Susumu FujiiAkihide Kuwabara
Mar 7, 2021·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Jakub J ZakrzewskiSzymon Chorazy
Apr 20, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Michał HeczkoBeata Nowicka
Apr 21, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Meng-Hua LiMei-Jin Lin
Jun 3, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Shintaro KawabataShin-Ichi Ohkoshi
Jul 24, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Emilia Kuzniak-GlanowskaRobert Podgajny
Sep 10, 2021·Chemical Communications : Chem Comm·Michał Magott, Dawid Pinkowicz
Sep 29, 2021·Physical Chemistry Chemical Physics : PCCP·Sophia KlokishnerMarianna Roman
Oct 1, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Yongfei LiHaiquan Tian
Nov 4, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Agnieszka PuzanSzymon Chorazy

❮ Previous
Next ❯

Methods Mentioned

BETA
X-ray
circular dichroism
irradiating
NMR

Software Mentioned

CTIST

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Angewandte Chemie
Eugenio CoronadoJaume Veciana
Topics in Current Chemistry
Nans RoquesJaume Veciana
Science Progress
Dawid PinkowiczMirosław Arczyński
Chemical Society Reviews
Joel S Miller, Dante Gatteschi
© 2021 Meta ULC. All rights reserved