Olefin ring closing metathesis and hydrosilylation reaction in aqueous medium by Grubbs second generation ruthenium catalyst

The Journal of Organic Chemistry
Vivek Polshettiwar, Rajender S Varma

Abstract

The Grubbs second generation ruthenium catalyst was shown to catalyze various olefin ring closing metathesis and hydrosilylation reactions in aqueous medium. Reactions proceeded in pure water without any additives or cosolvents, in a short period of time. We found that inhomogeneity of the reaction mixture does not prevent high conversion (70-95%) of the products in both reactions.

References

Feb 15, 2001·Accounts of Chemical Research·T M Trnka, R H Grubbs
Jun 17, 2005·Organic Letters·Cara L JenkinsRonald T Raines
Jun 6, 2007·Angewandte Chemie·Jason P Jordan, Robert H Grubbs
Jul 21, 2007·Angewandte Chemie·Hervé ClavierSteven P Nolan
Aug 19, 2007·The Journal of Organic Chemistry·Vivek Polshettiwar, Rajender S Varma
Apr 19, 2008·Accounts of Chemical Research·Vivek Polshettiwar, Rajender S Varma
Jul 24, 2008·Chemical Society Reviews·Vivek Polshettiwar, Rajender S Varma

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Citations

Dec 3, 2008·Chemical Communications : Chem Comm·Vivek PolshettiwarRajender S Varma
Mar 26, 2009·Chemical Communications : Chem Comm·Vivek PolshettiwarRajender S Varma
Sep 2, 2011·Chemical & Pharmaceutical Bulletin·Hue Thi My VanWon-Jea Cho
Feb 3, 2011·Beilstein Journal of Organic Chemistry·Didier AstrucJaime Ruiz
Jan 15, 2013·Tetrahedron Letters·Yinan Zhang, Richard B Silverman
Sep 8, 2010·Chemistry : a European Journal·Abdou K DialloDidier Astruc
Mar 27, 2013·Chemical Society Reviews·Manoj B GawandeRajender S Varma
Sep 4, 2015·Chemistry : a European Journal·Christopher A Brown, Varinder K Aggarwal
Oct 25, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Yuval VidavskyN Gabriel Lemcoff
May 11, 2012·Chemical Communications : Chem Comm·R B Nasir Baig, Rajender S Varma
Aug 24, 2013·Dalton Transactions : an International Journal of Inorganic Chemistry·Sanny VermaJacques Muzart
Feb 23, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Aziz FihriVivek Polshettiwar
Jan 25, 2020·Current Organic Synthesis·Navjeet Kaur
May 6, 2015·Chemical Reviews·Efrat LevinN Gabriel Lemcoff

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