On the reaction of GeCl2 ·dioxane with KFeCp(CO)2 : isolation and characterization of novel bimetallic clusters

Dalton Transactions : an International Journal of Inorganic Chemistry
Lars PreißingAndreas Schnepf

Abstract

The reaction of GeCl2·dioxane with KFeCp(CO)2 gives the polyhedral cluster compounds Ge6[FeCp(CO)2]61, Ge6[FeCp(CO)2]6Cl23 and Ge6[FeCp(CO)2]4[Fe2Cp2(CO)3]25. Quantum chemical calculations indicate that the substitution of a halide substituent in GeCl2 by FeCp(CO)2 favours the formation of oligomers with Ge-Ge bonds, giving access to polyhedral cluster compounds from easily accessible starting materials.

References

Sep 15, 1988·Physical Review A: General Physics·A D Becke
Jun 15, 1986·Physical Review. B, Condensed Matter·J P Perdew
Nov 21, 2007·Dalton Transactions : an International Journal of Inorganic Chemistry·Christian Schenk, Andreas Schnepf
Oct 1, 2008·Inorganic Chemistry·Marco BeckerDariush Hinderberger
Dec 6, 2008·Chemistry : a European Journal·Pekka Pyykkö, Michiko Atsumi
Aug 28, 2012·Journal of the American Chemical Society·Kai AbersfelderDavid Scheschkewitz
Jan 31, 2013·Angewandte Chemie·Shintaro IshidaSoichiro Kyushin
May 28, 2015·Angewandte Chemie·Kyohei OtsukaSoichiro Kyushin
Jan 11, 2018·Journal of the American Chemical Society·Yang LiChunming Cui

❮ Previous
Next ❯

Citations

Jul 28, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Nadine C MichenfelderAndreas-Neil Unterreiner
May 4, 2021·Angewandte Chemie·Alexa CaiseSimon Aldridge
Jul 22, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Lars PreißingAndreas Schnepf

❮ Previous
Next ❯

Methods Mentioned

BETA
NMR

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.