On the spontaneous induction of chirality in the preparation of Werner's complex cis-[CoBr(NH3)(en)2]Br2

Chemical Communications : Chem Comm
Fang GuoKenneth D M Harris

Abstract

The product obtained directly from the standard reaction to produce Werner's complex cis-[CoBr(NH3)(en)2]Br2 is shown, via structure determination from powder X-ray diffraction data, to be a racemic crystalline phase; implications of this observation in relation to previous reports that this reaction leads to significant enantiomeric excesses are discussed.

References

Apr 13, 1995·Nature·J L Bada
May 16, 2001·Angewandte Chemie·Kenneth D. M. HarrisBenson M. Kariuki
Sep 10, 2003·Journal of Computational Chemistry·Scott HabershonRoy L Johnston

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Citations

Mar 12, 2010·Chemical Communications : Chem Comm·Mark A SephtonPaul R Blakemore
Sep 15, 2012·Chemical Society Reviews·Edwin C Constable
Jan 20, 2021·Chemical Reviews·Thomas BuhseJean-Claude Micheau

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