Organoactinide-Catalyzed Monohydroboration of Carbodiimides

Chemistry : a European Journal
Heng LiuMoris S Eisen

Abstract

The organoactinide-catalyzed monohydroboration of carbodiimides is reported herein. The catalytic reactions proceed under very mild conditions in a highly atom-efficient and highly selective fashion to afford the corresponding monohydroborated N-borylformamidine products in high yields. A plausible mechanism is proposed based on stoichiometric and kinetic studies.

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Citations

Apr 21, 2018·Chemical Communications : Chem Comm·Alberto RamosDaniel García-Vivó
Feb 21, 2019·Chemical Communications : Chem Comm·Alberto RamosDaniel García-Vivó
Apr 4, 2019·Journal of Computational Chemistry·Ming-Xia Zhang, Hong-Liang Xu
Jul 11, 2019·Chemistry : a European Journal·Qiumiao ShenHerbert W Roesky
Feb 11, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Darren WillcoxRebecca L Melen
Sep 10, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Sayantani Saha, Moris S Eisen
May 20, 2021·Chemical Communications : Chem Comm·Shanmugam RevathiTapas Ghatak
Apr 25, 2021·Angewandte Chemie·Pradip Ghosh, Axel Jacobi von Wangelin

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