Organocatalytic hydroborylation promoted by N-heterocyclic olefins

Dalton Transactions : an International Journal of Inorganic Chemistry
Christian Hering-JunghansEric Rivard

Abstract

New complexes containing N-heterocyclic vinylene-stabilized [B2H5]+fragments were prepared, and surprisingly it was found that the precursor N-heterocyclic olefins (NHOs) could promote the mild (room temperature) catalytic hydroborylation of ketones and aldehydes. This finding represents an important addition to the burgeoning field of non-metal mediated catalysis.

References

Jun 25, 2010·Accounts of Chemical Research·Dietrich Gudat
May 13, 2011·Chemical Communications : Chem Comm·S M Ibrahim Al-RafiaEric Rivard
Apr 5, 2012·Chemical Communications : Chem Comm·Merle ArrowsmithGabriele Kociok-Köhn
Jun 12, 2013·Journal of the American Chemical Society·Marc-André CourtemancheFrédéric-Georges Fontaine
Jul 20, 2013·Journal of the American Chemical Society·Yan-Bo WangXiao-Bing Lu
Sep 6, 2013·Chemical Communications : Chem Comm·Rajendra S GhadwalGernot Frenking
Oct 5, 2013·Chemical Society Reviews·Alastair J J Lennox, Guy C Lloyd-Jones
Feb 15, 2014·Journal of the American Chemical Society·Terrance J HadlingtonCameron Jones
Jul 6, 2014·Angewandte Chemie·Paul A LummisEric Rivard
Jul 23, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Rajendra S GhadwalGernot Frenking
Aug 1, 2015·Science·Marc-André LégaréFrédéric-Georges Fontaine
Nov 27, 2015·Chemistry : a European Journal·Reece D Crocker, Thanh V Nguyen
Jan 12, 2016·Chemistry : a European Journal·Melanie W LuiEric Rivard
Mar 1, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Nathan R PaisleyEric Rivard
Jun 9, 2016·Chemistry : a European Journal·Lea Fohlmeister, Andreas Stasch
Oct 19, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Rajendra S Ghadwal
Aug 30, 2016·Organic Letters·Vineet Kumar JakharSharanappa Nembenna
Nov 20, 2016·Angewandte Chemie·Alessandro BismutoMichael J Cowley
Dec 13, 2016·Science·Douglas W Stephan
Apr 19, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Melanie W LuiEric Rivard
May 17, 2017·Angewandte Chemie·Christian Hering-JunghansEric Rivard

❮ Previous
Next ❯

Citations

May 16, 2019·Chemistry : a European Journal·Ian C WatsonEric Rivard
Oct 3, 2019·Chemical Communications : Chem Comm·Chengkai LiYuetao Zhang
Sep 14, 2019·Chemical Communications : Chem Comm·Stefan Naumann
Jan 12, 2019·The Journal of Organic Chemistry·Robin SchuldtStefan Naumann
Sep 10, 2020·The Journal of Organic Chemistry·Zengyu ZhangXiaoyu Yan

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.