Origin of SMM behaviour in an asymmetric Er(III) Schiff base complex: a combined experimental and theoretical study

Chemical Communications : Chem Comm
Chinmoy DasMaheswaran Shanmugam

Abstract

An asymmetric erbium(III) Schiff base complex [Er(HL)2(NO3)3] was synthesized which shows SMM behaviour with an Ueff of 5.2 K. Dipolar interaction in 1 significantly reduced upon dilution which increases the barrier height to 51.5 K. Ab initio calculations were performed to shed light on the mechanism of magnetization relaxation.

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Citations

Jan 27, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Apoorva UpadhyayMaheswaran Shanmugam
Mar 11, 2016·Chemistry : a European Journal·Eva LucacciniLorenzo Sorace
Sep 26, 2015·Chemistry : a European Journal·Kuduva R VigneshGopalan Rajaraman
Sep 19, 2015·Chemistry : a European Journal·Chinmoy DasMaheswaran Shanmugam
Aug 12, 2015·Chemistry : a European Journal·Saurabh Kumar SinghGopalan Rajaraman
Feb 27, 2016·Chemistry : a European Journal·Veacheslav Vieru, Liviu F Chibotaru
Apr 6, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Susanta HazraSasankasekhar Mohanta
Sep 9, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Adam GorczyńskiRobert Podgajny
May 14, 2016·Chemical Communications : Chem Comm·Sandeep K GuptaRamaswamy Murugavel
Jul 2, 2016·Chemical Communications : Chem Comm·Tulika Gupta, Gopalan Rajaraman
Feb 9, 2017·Chemistry : a European Journal·Apoorva UpadhyayMaheswaran Shanmugam
Aug 30, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Saurabh Kumar SinghGopalan Rajaraman
Jun 21, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Amit ChakrabortyVadapalli Chandrasekhar
Dec 13, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Júlia MayansAlbert Escuer
Aug 1, 2016·Chemical Science·Sandeep K GuptaRamaswamy Murugavel
Dec 20, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Peipei CenEmilio Pardo
Sep 15, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Lin JiangShiping Yan

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