Ortho C-H Acylation of Aryl Iodides by Palladium/Norbornene Catalysis

Angewandte Chemie
Zhe DongGuangbin Dong

Abstract

Reported herein is a palladium/norbornene-catalyzed ortho-arene acylation of aryl iodides by a Catellani-type C-H functionalization. This transformation is enabled by isopropyl carbonate anhydrides, which serve as both an acyl cation equivalent and a hydride source.

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Citations

Oct 12, 2016·Journal of the American Chemical Society·Masahiro Murakami, Naoki Ishida
Oct 8, 2016·Journal of the American Chemical Society·Peng WangJin-Quan Yu
Jan 7, 2017·Chemical Reviews·Dong-Su KimChul-Ho Jun
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Mar 21, 2018·Chemical Communications : Chem Comm·Ce LiuYong-Min Liang
Apr 27, 2018·Angewandte Chemie·Shuqing ChenQianghui Zhou
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Jul 15, 2020·Chemical Communications : Chem Comm·Bo-Sheng ZhangYong-Min Liang
Jul 6, 2020·Nature Communications·Rehanguli RuziJin Xie
Sep 7, 2019·Chemical Science·Uttam DuttaDebabrata Maiti
Jan 20, 2021·Organic Letters·Cui-Tian WangYong-Min Liang
Apr 8, 2021·Nature Communications·Qing-Yuan MengArmido Studer
Dec 17, 2019·Chemical Science·Wai Chung Fu, Fuk Yee Kwong
Jul 1, 2021·Chemical Society Reviews·Binlin ZhaoZhuangzhi Shi
Jul 13, 2021·Organic Letters·Ya-Nan DingYong-Min Liang
Apr 26, 2019·Chemical Reviews·Jianchun Wang, Guangbin Dong
Jun 16, 2018·Journal of the American Chemical Society·Zhe DongGuangbin Dong
Apr 25, 2019·Organic Letters·Peng WangQianghui Zhou
Apr 3, 2020·Organic Letters·Alexander J Rago, Guangbin Dong

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