Oxidant-free oxidative gold catalysis: the new paradigm in cross-coupling reactions

Chemical Communications : Chem Comm
Manjur O AkramNitin T Patil

Abstract

The construction of C-C and C-X (X = hetero atom) bonds is the core aspect for the assembly of molecules. In this regard, late transition-metal-catalyzed cross-coupling reactions have retained their dominance for decades. Lately, gold catalysts have been emerging as a reliable contender for such transformations owing to the recent findings that reveal gold's potential beyond carbophilic π-Lewis acid. The newfound ability of gold to undergo redox transformations under certain circumstances has allowed us to explore gold catalysts as a viable alternative to other late transition-metals for efficient construction of cross-coupled products. This feature article critically presents an overview of all the redox neutral cross-coupling reactions enabled by gold catalysis, which we believe would stimulate further research activities in this promising area.

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Citations

Oct 8, 2019·Chemistry, an Asian Journal·Shashank P SanchetiNitin T Patil
Sep 26, 2019·Angewandte Chemie·Svenja TaschinskiJohannes E M N Klein
Oct 12, 2019·Chemical Communications : Chem Comm·Jonas HimmelstrupSøren Kramer
Jan 22, 2020·Organic & Biomolecular Chemistry·Lingchun ZhangJun Sun
Oct 18, 2019·Chemistry : a European Journal·Ignacio Medina-MercadoSusana Porcel
Feb 25, 2020·Chemical Communications : Chem Comm·Somsuvra BanerjeeNitin T Patil
Jan 18, 2020·Angewandte Chemie·Jamie A CadgeChristopher A Russell
Jan 18, 2020·ChemSusChem·Fredric J L IngnerLukasz T Pilarski
Mar 24, 2020·Angewandte Chemie·Chetan C ChintawarNitin T Patil
Jul 16, 2020·Chemical Communications : Chem Comm·Akash G TatheNitin T Patil
May 22, 2020·Angewandte Chemie·Mathilde RigouletDidier Bourissou
Aug 5, 2020·Angewandte Chemie·Shuyao ZhangXiaodong Shi
Jun 27, 2019·Chemical Communications : Chem Comm·Abiola Azeez JimohXiaodong Shi
Jun 2, 2020·Chemistry : a European Journal·Susana Porcel, Ignacio Medina-Mercado
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Jan 27, 2019·Journal of the American Chemical Society·Weipeng LiChengjian Zhu
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Jun 9, 2020·Organic Letters·Somsuvra BanerjeeNitin T Patil
Oct 30, 2020·Accounts of Chemical Research·Christoph Fricke, Franziska Schoenebeck
Jul 27, 2021·Chemistry : a European Journal·Riccardo BonsignoreAngela Casini

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Methods Mentioned

BETA
NMR

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