Oxidative addition of carbon-carbon bonds to gold

Angewandte Chemie
Maximilian JoostDidier Bourissou

Abstract

The oxidative addition of strained CC bonds (biphenylene, benzocyclobutenone) to DPCb (diphosphino-carborane) gold(I) complexes is reported. The resulting cationic organogold(III) complexes have been isolated and fully characterized. Experimental conditions can be adjusted to obtain selectively acyl gold(III) complexes resulting from oxidative addition of either the C(aryl)C(O) or C(alkyl)C(O) bond of benzocyclobutenone. DFT calculations provide mechanistic insight into this unprecedented transformation.

References

Dec 14, 2004·Chemical Society Reviews·Chul-Ho Jun
Jul 8, 2009·Organic & Biomolecular Chemistry·Tobias Seiser, Nicolai Cramer
Dec 5, 2009·Organic Letters·Min JiangYuxue Li
May 22, 2010·Organic & Biomolecular Chemistry·Willem-Jan van Zeist, F Matthias Bickelhaupt
Oct 19, 2010·Chemical Communications : Chem Comm·Masahiro Murakami, Takanori Matsuda
Jul 21, 2011·Angewandte Chemie·Pauline GualcoDidier Bourissou
Oct 10, 2012·Journal of the American Chemical Society·Jonathan M DarmonPaul J Chirik
May 7, 2013·Journal of the American Chemical Society·Yusuke MasudaMasahiro Murakami
Jun 28, 2013·Angewandte Chemie·Chong QinNing Jiao
Aug 22, 2013·Journal of the American Chemical Society·Miriam A BowringT Don Tilley
Aug 27, 2013·Journal of the American Chemical Society·Nicolas LassauqueDidier Bourissou
Sep 11, 2013·Chemical Society Reviews·Michel Etienne, Andrew S Weller
Nov 15, 2013·Angewandte Chemie·Morgane Gaydou, Antonio M Echavarren
Nov 19, 2013·Topics in Current Chemistry·William D Jones
Dec 7, 2013·Angewandte Chemie·Maximilian JoostDidier Bourissou
Jan 18, 2014·Journal of the American Chemical Society·Johannes GuentherDidier Bourissou
Jan 24, 2014·Nature Chemistry·William J WolfF Dean Toste
Feb 13, 2014·Angewandte Chemie·Laetitia SouillartNicolai Cramer
Apr 5, 2014·Chemical Society Reviews·Israel Fernández, F Matthias Bickelhaupt
Apr 12, 2014·Journal of the American Chemical Society·Naoki IshidaMasahiro Murakami
Oct 1, 2014·Journal of the American Chemical Society·Maximilian JoostDidier Bourissou
Apr 1, 1999·Angewandte Chemie·Boris Rybtchinski, David Milstein
Jul 1, 2014·Organic Chemistry Frontiers : an International Journal of Organic Chemistry·Alpay DermenciGuangbin Dong

❮ Previous
Next ❯

Citations

Jun 16, 2016·Journal of the American Chemical Society·Jiaxiang ChuGuy Bertrand
Oct 19, 2016·Accounts of Chemical Research·Matthew N HopkinsonFrank Glorius
Aug 18, 2016·Journal of the American Chemical Society·Feriel RekhroukhDidier Bourissou
Oct 12, 2016·Journal of the American Chemical Society·Masahiro Murakami, Naoki Ishida
Dec 13, 2016·Journal of the American Chemical Society·Tom J A CorrieGuy C Lloyd-Jones
Feb 3, 2016·Angewandte Chemie·Feriel RekhroukhDidier Bourissou
Nov 24, 2016·Chemistry, an Asian Journal·Daniel Mendoza-EspinosaOscar R Suárez-Castillo
Oct 6, 2015·Chemical Communications : Chem Comm·Marta Ayerbe GarciaRené Peters
Dec 6, 2017·Angewandte Chemie·Jessica Rodriguez, Didier Bourissou
Feb 17, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Julia HolzRené Peters
Apr 4, 2018·Physical Chemistry Chemical Physics : PCCP·Narendra P Arasu, Héctor Vázquez
Dec 14, 2017·Angewandte Chemie·Abdallah ZeineddineDidier Bourissou
Apr 21, 2016·Chemical Communications : Chem Comm·Long HuangA Stephen K Hashmi
May 18, 2016·Chemical Communications : Chem Comm·Eric Omar Asomoza-SolísSusana Porcel
Aug 19, 2017·Dalton Transactions : an International Journal of Inorganic Chemistry·Carlo Alberto GaggioliPaola Belanzoni
May 31, 2018·Chemistry : a European Journal·Charlie BlonsDidier Bourissou
Jan 16, 2016·Angewandte Chemie·Maximilian JoostDidier Bourissou
Feb 1, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Tao WangJianhui Wang
Jun 22, 2019·Chemical Communications : Chem Comm·Miquel NavarroDidier Bourissou
Feb 6, 2020·Chemistry : a European Journal·Guang-Ao YuChang-Duo Yue
Sep 16, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Maryne DuvalDidier Bourissou
Jul 11, 2020·Angewandte Chemie·Alexandre GenouxCristina Nevado
Sep 20, 2017·Nature Communications·Abdallah ZeineddineDidier Bourissou
Jun 15, 2016·Chemistry : a European Journal·Marco BaronLucia Caporaso
Jan 1, 2018·Topics in Catalysis·Alexander S GentlemanStuart R Mackenzie
Jan 21, 2017·Chemistry : a European Journal·Benito AlcaideTeresa Martínez Del Campo
Jan 1, 2016·Chemical Science·Adrian Tlahuext-AcaFrank Glorius
Feb 10, 2021·Chemical Reviews·Raquel P Herrera, M Concepción Gimeno
Mar 30, 2021·Chemistry : a European Journal·Rémi JouhannetPierre de Frémont
Jun 26, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Wolfram Feuerstein, Frank Breher
Apr 4, 2020·Organic Letters·Joan G MayansAntonio M Echavarren

❮ Previous
Next ❯

Related Concepts

Trending Feeds

COVID-19

Coronaviruses encompass a large family of viruses that cause the common cold as well as more serious diseases, such as the ongoing outbreak of coronavirus disease 2019 (COVID-19; formally known as 2019-nCoV). Coronaviruses can spread from animals to humans; symptoms include fever, cough, shortness of breath, and breathing difficulties; in more severe cases, infection can lead to death. This feed covers recent research on COVID-19.

Blastomycosis

Blastomycosis fungal infections spread through inhaling Blastomyces dermatitidis spores. Discover the latest research on blastomycosis fungal infections here.

Nuclear Pore Complex in ALS/FTD

Alterations in nucleocytoplasmic transport, controlled by the nuclear pore complex, may be involved in the pathomechanism underlying multiple neurodegenerative diseases including Amyotrophic Lateral Sclerosis and Frontotemporal Dementia. Here is the latest research on the nuclear pore complex in ALS and FTD.

Applications of Molecular Barcoding

The concept of molecular barcoding is that each original DNA or RNA molecule is attached to a unique sequence barcode. Sequence reads having different barcodes represent different original molecules, while sequence reads having the same barcode are results of PCR duplication from one original molecule. Discover the latest research on molecular barcoding here.

Chronic Fatigue Syndrome

Chronic fatigue syndrome is a disease characterized by unexplained disabling fatigue; the pathology of which is incompletely understood. Discover the latest research on chronic fatigue syndrome here.

Evolution of Pluripotency

Pluripotency refers to the ability of a cell to develop into three primary germ cell layers of the embryo. This feed focuses on the mechanisms that underlie the evolution of pluripotency. Here is the latest research.

Position Effect Variegation

Position Effect Variagation occurs when a gene is inactivated due to its positioning near heterochromatic regions within a chromosome. Discover the latest research on Position Effect Variagation here.

STING Receptor Agonists

Stimulator of IFN genes (STING) are a group of transmembrane proteins that are involved in the induction of type I interferon that is important in the innate immune response. The stimulation of STING has been an active area of research in the treatment of cancer and infectious diseases. Here is the latest research on STING receptor agonists.

Microbicide

Microbicides are products that can be applied to vaginal or rectal mucosal surfaces with the goal of preventing, or at least significantly reducing, the transmission of sexually transmitted infections. Here is the latest research on microbicides.

Related Papers

Chemical Communications : Chem Comm
Madeleine LivendahlAntonio M Echavarren
© 2022 Meta ULC. All rights reserved