Oxidative cleavage of allyl ethers by an oxoammonium salt

Organic & Biomolecular Chemistry
Christopher B KellyNicholas E Leadbeater

Abstract

A method to oxidatively cleave allyl ethers to their corresponding aldehydes mediated by an oxoammonium salt is described. Using a biphasic solvent system and mild heating, cleavage proceeds readily, furnishing a variety of α,β-unsaturated aldehydes and ketones.

References

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Apr 26, 2013·Organic Letters·Christopher B KellyNicholas E Leadbeater
May 28, 2013·The Journal of Organic Chemistry·Renate RohlmannOlga García Mancheño
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Citations

Sep 22, 2016·Angewandte Chemie·Shota NagasawaYoshiharu Iwabuchi
Mar 11, 2017·Organic & Biomolecular Chemistry·Shelli A MillerNicholas E Leadbeater
Jun 7, 2017·The Journal of Organic Chemistry·Pieter J GilissenFloris P J T Rutjes
Jul 8, 2021·Organic & Biomolecular Chemistry·Rowan I L MeadorJohn D Chisholm
Nov 26, 2021·Chemistry : a European Journal·Jenna L MillerPaul E Floreancig

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