Oxoborane (RBO) Complexation and Concomitant Electrophilic Bond Activation Processes

Chemistry : a European Journal
Anindya K SwarnakarEric Rivard

Abstract

Donor-acceptor complexes of the oxoboranes ClB=O and HOB=O were synthesized and each feature short multiply bonded B=O linkages. The retention of high Lewis acidic character within these encapsulated monomeric oxoboranes was manifested by their ability to support C-F and Si-O bond activation/functionalization. The reported ClB=O complexes can be regarded as synthetic surrogates of the [BO]+ cation, an inorganic analogue of CO.

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Citations

Jul 14, 2018·Chemistry : a European Journal·Matthew M D RoyEric Rivard
May 14, 2020·Angewandte Chemie·Anne-Frédérique PécharmanMary F Mahon
May 31, 2019·Chemistry : a European Journal·Ryan R MaarJoe B Gilroy
Jul 15, 2020·Angewandte Chemie·Ying Kai Loh, Simon Aldridge
May 19, 2021·Dalton Transactions : an International Journal of Inorganic Chemistry·Rui LiuWenyuan Wang
Jun 2, 2021·Angewandte Chemie·Hanqiang WangZuowei Xie
Oct 24, 2018·Inorganic Chemistry·Yang ZhengJincai Wu
May 3, 2019·Journal of the American Chemical Society·Ying Kai LohSimon Aldridge
Jul 4, 2018·Chemical Reviews·Vitaly NesterovShigeyoshi Inoue
Nov 10, 2020·Journal of the American Chemical Society·Chaohuang ChenGerhard Erker
Sep 26, 2019·Inorganic Chemistry·Rui GuoLingbing Kong

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