Palladium-catalyzed electrophilic allylation reactions via bis(allyl)palladium complexes and related intermediates

Chemistry : a European Journal
Kálmán J Szabó

Abstract

The synthetic scope of the allyl-palladium chemistry can be extended to involve electrophilic reagents. The greatest challenge in these reactions is the catalytic generation of an allyl-palladium intermediate incorporating a nucleophilic allyl moiety. A vast majority of the published reactions that involve palladium-catalyzed allylation of electrophiles proceed via bis(allyl)palladium intermediates. The eta(1)-moiety of the bis(allyl)palladium intermediates reacts with electrophiles, including aldehydes, imines, or Michael acceptors. Recently, catalytic electrophilic allylations via mono-allylpalladium complexes were also presented by employment of so-called "pincer complex" catalysts.

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Citations

May 18, 2016·Organic Letters·Tsuyoshi MitaYoshihiro Sato
Mar 16, 2017·Journal of the American Chemical Society·Wei BaoUwe Schneider
Dec 15, 2006·Organic Letters·Chad D Hopkins, Helena C Malinakova
Apr 16, 2015·Chemical Communications : Chem Comm·Hirokazu TsukamotoTakayuki Doi
Jul 2, 2005·Chemistry : a European Journal·Johan KjellgrenKálmán J Szabó
Aug 6, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Nicklas Selander, Kálmán J Szabó
Mar 4, 2011·Chemistry : a European Journal·Alba MillánJuan M Cuerva
Jul 26, 2019·Chemical Science·Ding-Wei JiVy M Dong
Aug 22, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Arun KumarAjai K Singh
Sep 30, 2015·Chemistry : a European Journal·Tsuyoshi MitaYoshihiro Sato
Sep 12, 2018·Beilstein Journal of Organic Chemistry·Tsuyoshi MitaYoshihiro Sato
Apr 9, 2013·Angewandte Chemie·Crispin Lichtenberg, Jun Okuda
Apr 24, 2007·The Journal of Organic Chemistry·Olivier PiechaczykPascal Le Floch
Dec 22, 2007·Chemical Reviews·Sylvain Darses, Jean-Pierre Genet
Jan 11, 2011·Organometallics·Jianguo WuTimothy J Schmeier
Nov 23, 2010·Chemical Reviews·Nicklas Selander, Kálmán J Szabó
Jan 18, 2011·Chemical Reviews·Jimmie D WeaverJon A Tunge
Oct 20, 2017·Organic Letters·Tsuyoshi MitaYoshihiro Sato
Nov 27, 2018·Organic Letters·Tsuyoshi MitaYoshihiro Sato
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May 11, 2013·Journal of the American Chemical Society·Genping HuangFahmi Himo
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Jan 27, 2007·The Journal of Organic Chemistry·Fabio Pichierri, Yoshinori Yamamoto
Oct 15, 2021·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Yoshikazu Horino, Toshinobu Korenaga

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