Palladium-catalyzed Hiyama coupling reaction of arylsulfonyl hydrazides under oxygen

Organic & Biomolecular Chemistry
Hui MiaoYang Li

Abstract

Palladium-catalyzed Hiyama cross-coupling reactions of various arylsulfonyl hydrazides with a wide variety of aryl silanes have been achieved in good to excellent yields under simple conditions. The newly developed catalytic system does not require the use of expensive silver- or copper-based stoichiometric oxidants and can be accelerated by the addition of TBAT under an atmosphere of oxygen. The reported Hiyama-type coupling reactions are tolerant to common functional groups, making these transformations attractive alternatives to the traditional cross-coupling approaches.

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Citations

Nov 5, 2015·Organic & Biomolecular Chemistry·Sirilata YotphanVichai Reutrakul
Oct 21, 2015·Organic Letters·Arvind Kumar, Bhahwal Ali Shah
May 28, 2020·Chemical Society Reviews·Jiang LouZhengkun Yu
Jul 15, 2016·Chemical Record : an Official Publication of the Chemical Society of Japan ... [et Al.]·Francisco FoubeloMiguel Yus
Dec 29, 2020·Organic Letters·Shan YangYingsheng Zhao
Mar 6, 2018·The Journal of Organic Chemistry·Mengting MengChenze Qi

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