Palladium-catalyzed hydroalkylation of methylenecyclopropanes with simple hydrazones.

Chemical Science
Jinzhong YaoChao-Jun Li

Abstract

A palladium-catalyzed hydroalkylation reaction of methylenecyclopropanes via highly selective C-C σ-bond scission was achieved under mild conditions, in which simple hydrazones served as carbanion equivalents. This method featured good functional group compatibility, affording high yields of C-alkylated terminal alkenes.

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Citations

Aug 13, 2021·Chemical Society Reviews·Xi-Jie DaiChao-Jun Li
Sep 4, 2021·The Journal of Organic Chemistry·Siyi LuoChao-Jun Li
May 16, 2021·Angewandte Chemie·Shun Wang, Burkhard König

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Methods Mentioned

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