Palladium-catalyzed regioselective intramolecular coupling of o-carborane with aromatics via direct cage B-H activation

Journal of the American Chemical Society
Yangjian Quan, Zuowei Xie

Abstract

Palladium-catalyzed intramolecular coupling of o-carborane with aromatics via direct cage B-H bond activation has been achieved, leading to the synthesis of a series of o-carborane-functionalized aromatics in high yields with excellent regioselectivity. In addition, the site selectivity can also be tuned by the substituents on cage carbon atom.

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