Palladium-catalyzed regioselective synthesis of B(4,5)- or B(4)-substituted o-carboranes containing α,β-unsaturated carbonyls.

Organic & Biomolecular Chemistry
Chuyi ZhangJian Lu

Abstract

With the help of a carboxylic acid directing group, Pd-catalyzed regioselective synthesis of B(4,5)- or B(4)-substituted o-carboranes containing α,β-unsaturated carbonyls has been reported. The -COOH, removed during the course of the reaction, is responsible for controlling the regioselectivity. The desired products could be obtained in moderate to good yields.

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Citations

Dec 30, 2021·Inorganic Chemistry·Yatong FuJu-You Lu

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Methods Mentioned

BETA
neutron capture therapy
X-ray

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