Pb9CdCdPb9]6-: a Zintl cluster anion with an unsupported cadmium-cadmium bond

Chemical Communications : Chem Comm
Binbin ZhouJose M Goicoechea

Abstract

Reaction of an ethylenediamine solution of the intermetallic Zintl phase K4Pb9 with dimesitylcadmium yielded the dimeric Zintl ion [Pb9Cd-CdPb9]6- in low crystalline yield. The cluster anion exhibits a Cd-Cd bond and was structurally characterised by single crystal X-ray diffraction in [K(2,2,2-crypt)]6[Cd2Pb18].2en (1). DFT was also used to explore the bonding in the hexa-anionic cluster.

References

Jul 18, 2001·Journal of the American Chemical Society·E D JemmisP D Pancharatna
Aug 25, 2004·Science·Gerard Parkin
Aug 25, 2004·Science·Irene ResaAngeles Monge
Aug 25, 2005·Journal of the American Chemical Society·Yuzhong WangGregory H Robinson
Jan 18, 2007·Journal of the American Chemical Society·Abdessamad GrirraneRichard A Andersen
May 5, 2007·Angewandte Chemie·Igor L FedushkinGeorgy K Fukin
Oct 11, 2007·Chemical Communications : Chem Comm·Yi-Chou TsaiJen-Shiang K Yu
Apr 18, 2008·Chemistry : a European Journal·Sandra ScharfeKlaus Ruhland
Jul 18, 2008·Angewandte Chemie·Ernesto Carmona, Agustín Galindo
Dec 17, 2008·Dalton Transactions : an International Journal of Inorganic Chemistry·Mark S Denning, Jose M Goicoechea
Feb 5, 2009·Angewandte Chemie·Jian-Qiang WangThomas F Fässler
Feb 7, 2009·Journal of the American Chemical Society·Binbin ZhouJose M Goicoechea
May 8, 2009·Dalton Transactions : an International Journal of Inorganic Chemistry·Binbin ZhouJose M Goicoechea
Jun 14, 1999·Angewandte Chemie·Evgeny Todorov, Slavi C Sevov

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Citations

Aug 6, 2011·Inorganic Chemistry·Binbin ZhouJose M Goicoechea
Feb 28, 2015·Chemical Communications : Chem Comm·Matthew P BlakePhilip Mountford
May 19, 2018·Chemistry : a European Journal·Chao LiuZhong-Ming Sun
Apr 2, 2011·Angewandte Chemie·Sandra ScharfeThomas F Fässler
Aug 12, 2018·Angewandte Chemie·Kerstin MayerRoland A Fischer
Mar 3, 2012·Chemical Society Reviews·Tianshu LiPeter W Roesky
Mar 7, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Sukhendu MandalAyusman Sen
Aug 26, 2016·Angewandte Chemie·Robert J WilsonStefanie Dehnen
May 5, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·C WallachT F Fässler
Jul 25, 2012·Chemical Communications : Chem Comm·Markus WaibelThomas F Fässler
Oct 8, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Chao ZhangJohn E McGrady
Sep 4, 2012·Dalton Transactions : an International Journal of Inorganic Chemistry·Sukhendu MandalAyusman Sen
Mar 5, 2014·Chemical Communications : Chem Comm·Yi WangLi Xu
Dec 8, 2017·Chemical Communications : Chem Comm·D J WebbJ R Fulton
Mar 9, 2021·Accounts of Chemical Research·Yi WangZhong-Ming Sun

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