PbCdF(SeO3 )(NO3 ): A Nonlinear Optical Material Produced by Synergistic Effect of Four Functional Units

Inorganic Chemistry
Yun-Xiang MaJiang-Gao Mao

Abstract

A new nonlinear optical material, the first fluoride selenite nitrate PbCdF(SeO3)(NO3), was successfully synthesized by traditional solid state reactions. This compound crystallizes in the polar space group of Pca21, and its structure features a novel 2D layered structure consisting of 1D lead nitrate chains and 2D cadmium selenite layers. PbCdF(SeO3)(NO3) exhibits a phase-matchable SHG efficiency of about 2.6 times that of KDP and a wide band gap of 4.42 eV. Its laser damage threshold was measured to be 135.6 MW/cm2, which is comparative to that of the reported Li7(TeO3)3F with a short ultraviolet cutoff edge. Theoretical calculation confirmed that the synergistic effects of all the four functional units make PbCdF(SeO3)(NO3) a remarkable SHG material.

References

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Apr 11, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Jian-Han ZhangJiang-Gao Mao
May 22, 2018·Chemical Communications : Chem Comm·Xuehua DongGuohong Zou

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Citations

Jan 15, 2019·Chemistry : a European Journal·Ya-Ping GongJiang-Gao Mao
Jun 25, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Yanjun LiP Shiv Halasyamani
Feb 26, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Chao WuChi Zhang
Jun 12, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Fang Kong, Jiang-Gao Mao

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