Pd Nanocubes@ZIF-8: Integration of Plasmon-Driven Photothermal Conversion with a Metal-Organic Framework for Efficient and Selective Catalysis

Angewandte Chemie
Qihao YangHai-Long Jiang

Abstract

Composite nanomaterials usually possess synergetic properties resulting from the respective components and can be used for a wide range of applications. In this work, a Pd nanocubes@ZIF-8 composite material has been rationally fabricated by encapsulation of the Pd nanocubes in ZIF-8, a common metal-organic framework (MOF). This composite was used for the efficient and selective catalytic hydrogenation of olefins at room temperature under 1 atm H2 and light irradiation, and benefits from plasmonic photothermal effects of the Pd nanocube cores while the ZIF-8 shell plays multiple roles; it accelerates the reaction by H2 enrichment, acts as a "molecular sieve" for olefins with specific sizes, and stabilizes the Pd cores. Remarkably, the catalytic efficiency of a reaction under 60 mW cm(-2) full-spectrum or 100 mW cm(-2) visible-light irradiation at room temperature turned out to be comparable to that of a process driven by heating at 50 °C. Furthermore, the catalyst remained stable and could be easily recycled. To the best of our knowledge, this work represents the first combination of the photothermal effects of metal nanocrystals with the favorable properties of MOFs for efficient and selective catalysis.

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Citations

Apr 27, 2016·Journal of the American Chemical Society·Feng LuoBanglin Chen
May 12, 2017·Inorganic Chemistry·Feng-Ling YuanJian-Ping Lang
May 19, 2017·Chemical Society Reviews·Liyu ChenYingwei Li
Jun 18, 2017·Chemical Society Reviews·Qihao YangHai-Long Jiang
Jul 7, 2017·Chemistry : a European Journal·Ke JiangGuodong Qian
Mar 2, 2018·Dalton Transactions : an International Journal of Inorganic Chemistry·Liyu ChenYingwei Li
Dec 1, 2017·Molecules : a Journal of Synthetic Chemistry and Natural Product Chemistry·Wenlong XiangChang-Jun Liu
Oct 11, 2017·Chemistry : a European Journal·Vasudeva Rao Bakuru, Suresh Babu Kalidindi
Sep 20, 2017·Chemical Communications : Chem Comm·Yangke LongYunan Wang
Nov 28, 2017·Advanced Materials·Long JiaoQiang Xu
Mar 14, 2019·ChemSusChem·Vaishakh NairJuan Carlos Colmenares
Sep 13, 2019·Chemical Communications : Chem Comm·Ye LiuFengwei Huo
Jan 18, 2020·Chemical Communications : Chem Comm·Yong LiuWei Zhang
Apr 24, 2020·Chemical Communications : Chem Comm·Raffaele RiccoPaolo Falcaro

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