Pd NP-Loaded and Covalently Cross-Linked COF Membrane Microreactor for Aqueous CBs Dechlorination at Room Temperature

ACS Applied Materials & Interfaces
Bing-Jian YaoYu-Bin Dong

Abstract

We report an allyl-decorated and hydrazine-connected covalent organic framework (COF-AO, 1), which could support Pd nanoparticles (Pd NPs) to generate Pd@COF-AO, 2. The incorporation of 2 with thiol-functionalized polysiloxane (termed as PSI-SH) via thiol-ene click reaction provided the stand-alone and elastic membrane (3). The obtained COF-involved and Pd NP-loaded covalently linked membrane of 3 is robust, permanently porous, uniform, processable, and water permeable. Moreover, it can be used to construct highly efficient membrane-based microreactor for continuous-flow operation to catalyze chlorobenzenes (CBs) dechlorination in water at room temperature. The provided approach herein allows the processability and practical application of the powdered COF materials to be feasible.

References

Jun 10, 2000·The Science of the Total Environment·A A MehargD Osborn
Jun 19, 2001·Journal of Hazardous Materials·C SeignezP Peringer
Aug 22, 2002·Environmental Science & Technology·Qingzhong WuHarold D May
Nov 14, 2002·Chemical Reviews·Francisco AlonsoMiguel Yus
Oct 11, 2003·Organic Letters·Jonathan H ChongMark J MacLachlan
May 27, 2004·Journal of the American Chemical Society·Tetsuo IwasawaYasushi Tsuji
Dec 7, 2007·Journal of Hazardous Materials·Hun-Young Wee, Jeffrey A Cunningham
Feb 19, 2010·Angewandte Chemie·Charles E Hoyle, Christopher N Bowman
Jan 28, 2011·Journal of the American Chemical Society·G K Surya PrakashGeorge A Olah
Jul 5, 2011·Journal of the American Chemical Society·Fernando J Uribe-RomoOmar M Yaghi
Sep 1, 2011·Chemical Society Reviews·Angelica BalantaCarmen Claver
Oct 27, 2011·Journal of the American Chemical Society·San-Yuan DingWei Wang
Jun 15, 2012·Chemical Society Reviews·Amarajothi Dhakshinamoorthy, Hermenegildo Garcia
Jul 24, 2012·Chemical Society Reviews·Xiao FengDonglin Jiang
Oct 13, 2012·Chemical Society Reviews·San-Yuan Ding, Wei Wang
Mar 12, 2013·Environmental Science & Technology·Zohre Kurt, Jim C Spain
Mar 26, 2013·Journal of the American Chemical Society·Bishnu P BiswalRahul Banerjee
Sep 25, 2015·Chemical Reviews·Aicheng Chen, Cassandra Ostrom
Nov 15, 2016·Chemical Society Reviews·Yuan-Biao HuangRong Cao
Dec 31, 2016·Chemical Reviews·Saikat DasShilun Qiu
Jan 10, 2017·Advanced Materials·Sharath KandambethRahul Banerjee
Mar 4, 2017·Science·Christian S Diercks, Omar M Yaghi
Mar 4, 2017·Journal of the American Chemical Society·Shouvik MitraRahul Banerjee
Aug 19, 2017·Science·Enquan JinDonglin Jiang
Sep 7, 2017·Journal of the American Chemical Society·Kaushik DeyRahul Banerjee
Dec 19, 2017·Journal of the American Chemical Society·Torben SickThomas Bein

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Citations

Jun 13, 2019·Chemical Society Reviews·José L SeguraM Mar Ramos
Apr 26, 2020·Chemistry : a European Journal·Hui-Chao MaYu-Bin Dong
Aug 13, 2020·Angewandte Chemie·Banglin ChenHuanrong Li
Feb 27, 2021·Chemical Communications : Chem Comm·Yaohan ChenSuobo Zhang
Jun 24, 2020·Journal of the American Chemical Society·Hui-Chao MaYu-Bin Dong
Jan 26, 2022·ACS Applied Materials & Interfaces·Xiaomin RenQihua Yang
Jan 29, 2022·Physical Chemistry Chemical Physics : PCCP·Yao-Yin LouShi-Gang Sun

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