Abstract
A general strategy in terms of degradating and ion-exchange synthesis was used to design pentadecatungstotrivanadodiphosphoric heteropoly acid H(9)P(2)W(15)V(3)O(62)·28H(2)O with Dawson structure and excellent conductivity. The product was characterized by ICP-MS, IR, UV, XRD, (31)P NMR, TG-DTA and electrochemical impedance spectroscopy (EIS). The results indicate that H(9)P(2)W(15)V(3)O(62)·28H(2)O possesses the Dawson structure. EIS measurements show a high conductivity (3.64 × 10(-2) S cm(-1) at 26 °C and 75% relative humidity), with an activation energy of 31.34 kJ mol(-1) for proton conduction. Its mechanism for proton conduction is the Vehicle mechanism.
References
Apr 7, 2005·Journal of the American Chemical Society·Michael J JanikMatthew Neurock
May 7, 2005·Dalton Transactions : an International Journal of Inorganic Chemistry·C DablemontJ-C Tabet
Jan 23, 2009·Inorganic Chemistry·Masooma IbrahimUlrich Kortz
Feb 17, 2010·Journal of the American Chemical Society·Bing QinZhiyong Tang
May 4, 2010·Angewandte Chemie·Jun YanLeroy Cronin
Jun 16, 2010·Chemical Communications : Chem Comm·Hai-jun PangZhong-min Su
Jul 7, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Jun-ichi NambuAlan M Bond
Jul 16, 2010·Angewandte Chemie·Yuji KikukawaNoritaka Mizuno
Jul 30, 2010·Dalton Transactions : an International Journal of Inorganic Chemistry·Chun-Dan ZhangZhong-Min Su
Aug 6, 2010·Journal of the American Chemical Society·Jun YanLeroy Cronin
Nov 26, 2010·Chemical Communications : Chem Comm·Regina PalkovitsJoanna Procelewska
Mar 2, 2011·Advanced Materials·Amjad NisarXun Wang
Mar 17, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Benjamin P Burton-Pye, Lynn C Francesconi
Aug 6, 2011·Dalton Transactions : an International Journal of Inorganic Chemistry·Bassem S Bassil, Ulrich Kortz
Citations
Jun 2, 2015·ACS Applied Materials & Interfaces·Jian-Sheng LiEn-Bo Wang
Apr 5, 2017·Langmuir : the ACS Journal of Surfaces and Colloids·Xuefei WuWenfu Yan
Dec 6, 2016·Chemical Society Reviews·Xing MengHong-Jie Zhang
Mar 10, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Jian-Ping BaiZai-Ming Zhu
Feb 4, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Tianpei HuangWenfu Yan
Jun 29, 2016·Dalton Transactions : an International Journal of Inorganic Chemistry·Xuefei WuWenfu Yan
Nov 26, 2015·Dalton Transactions : an International Journal of Inorganic Chemistry·Xuefei WuLin Xu
Nov 16, 2019·Dalton Transactions : an International Journal of Inorganic Chemistry·Zhi-Yuan YaoXiao-Ming Ren
Sep 22, 2020·Dalton Transactions : an International Journal of Inorganic Chemistry·Di QuLixin Wu
May 8, 2015·Soft Matter·Tianpei HuangWenfu Yan
Aug 7, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Yunyan LiWenfu Yan
Nov 14, 2012·Chemical Communications : Chem Comm·Xin XuLi Xu
Oct 15, 2014·Physical Chemistry Chemical Physics : PCCP·Xuefei WuWenfu Yan
Aug 26, 2014·Dalton Transactions : an International Journal of Inorganic Chemistry·Jun MiaoQingyin Wu
Dec 11, 2019·Chemical Communications : Chem Comm·Shan ZhangShu-Xia Liu
Jun 9, 2021·Chemistry : a European Journal·Chunhui MaWeilin Chen
Jul 19, 2013·Inorganic Chemistry·Lu YangJingyang Niu